Molecular tectonics: on the role of counter-ions in the dimensionality of silver coordination networks

被引:60
作者
Pocic, D [1 ]
Planeix, JM [1 ]
Kyritsakas, N [1 ]
Jouaiti, A [1 ]
Hosseini, MW [1 ]
机构
[1] Univ Strasbourg, Chim Coordinat Organ Lab, UMR CNRS 7140, F-67000 Strasbourg, France
来源
CRYSTENGCOMM | 2005年 / 7卷
关键词
D O I
10.1039/b513138n
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The role played by different anions (XF6- (X = P, As, Sb), BF4-) on the connectivity of coordination networks formed by a combination of different silver salts and an organic tecton based on piperazine bearing two pyridine units has been studied in the crystalline phase by X-ray diffraction on single crystal. All four weakly coordinating anions lead to the formation of analogous 2-D coordination networks. For the isostructural anions XF6- (X = P, As, Sb) the crystals are isomorphous.
引用
收藏
页码:624 / 628
页数:5
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