Patterned polymer brushes via electrodeposited ATRP, ROMP, and RAFT initiators on colloidal template arrays

被引：15

作者：

Foster, Edward L. ^{[1
]}

Tria, Maria Celeste R. ^{[1
]}

Pernites, Roderick B. ^{[1
]}

Addison, Steven J. ^{[1
]}

Advincula, Rigoberto C. ^{[1
]}

机构：

[1] Univ Houston, Dept Chem & Chem Biomol Engn, Houston, TX 77204 USA

来源：

SOFT MATTER | 2012年 / 8卷 / 02期

关键词：

TRANSFER RADICAL POLYMERIZATION; FRAGMENTATION CHAIN TRANSFER; SOFT LITHOGRAPHY; SURFACE; FABRICATION; CRYSTALS; SILICA; CARBON; FILMS; OXIDE;

D O I：

10.1039/c1sm06406a

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We report the fabrication of patterned binary polymer brushes via colloidal particle templating combined with electrodeposited ATRP, RAFT, and ROMP initiators. From the hexagonally close-packed template and subsequent patterned arrays, surface-initiated polymerization (SIP) demonstrated novel non-lithographically and laterally patterned binary polymer brush composition.

引用

页码：353 / 359

页数：7

共 51 条

[1] Surface-initiated polymerization on nanopatterns fabricated by electron-beam lithography [J].

Ahn, SJ ;

Kaholek, M ;

Lee, WK ;

LaMattina, B ;

LaBean, TH ;

Zauscher, S .

ADVANCED MATERIALS, 2004, 16 (23-24) :2141-+

[2] Bioadhesion at micro-patterned stimuli-responsive polymer brushes [J].

Alarcón, CDH ;

Farhan, T ;

Osborne, VL ;

Huck, WTS ;

Alexander, C .

JOURNAL OF MATERIALS CHEMISTRY, 2005, 15 (21) :2089-2094

[3] Stimuli-responsive surfaces using polyampholyte polymer brushes prepared via atom transfer radical polymerization [J].

Ayres, Neil ;

Cyrus, Crystal D. ;

Brittain, William J. .

LANGMUIR, 2007, 23 (07) :3744-3749

[4] Monitoring Block-Copolymer Crossover-Chemistry in ROMP: Catalyst Evaluation via Mass-Spectrometry (MALDI) [J].

Binder, Wolfgang H. ;

Pulamagatta, Bhanuprathap ;

Kir, Onur ;

Kurzhals, Steffen ;

Barqawi, Haitham ;

Tanner, Susanne .

MACROMOLECULES, 2009, 42 (24) :9457-9466

[5] Homogeneous metathesis polymerization by well-defined group VI and group VIII transition-metal alkylidenes: Fundamentals and applications in the preparation of advanced materials [J].

Buchmeiser, MR .

CHEMICAL REVIEWS, 2000, 100 (04) :1565-1604

[6] Synthesis of hydrophilic polymer-grafted ultrafine inorganic oxide particles in protic media at ambient temperature via atom transfer radical polymerization: use of an electrostatically adsorbed polyelectrolytic macroinitiator [J].

Chen, XY ;

Armes, SP ;

Greaves, SJ ;

Watts, JF .

LANGMUIR, 2004, 20 (03) :587-595

[7] Synthesis and electrochromic properties of mesoporous tungsten oxide [J].

Cheng, W ;

Baudrin, E ;

Dunn, B ;

Zink, JI .

JOURNAL OF MATERIALS CHEMISTRY, 2001, 11 (01) :92-97

[8] Living free-radical polymerization by reversible addition-fragmentation chain transfer: The RAFT process [J].

Chiefari, J ;

Chong, YK ;

Ercole, F ;

Krstina, J ;

Jeffery, J ;

Le, TPT ;

Mayadunne, RTA ;

Meijs, GF ;

Moad, CL ;

Moad, G ;

Rizzardo, E ;

Thang, SH .

MACROMOLECULES, 1998, 31 (16) :5559-5562

[9] Fabrication approaches for generating complex micro- and nanopatterns on polymeric surfaces [J].

del Campo, Aranzazu ;

Arzt, Eduard .

CHEMICAL REVIEWS, 2008, 108 (03) :911-945

[10]

Deutsch M, 2000, ADV MATER, V12, P1176, DOI 10.1002/1521-4095(200008)12:16<1176::AID-ADMA1176>3.0.CO

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