Properties of titanium glykolates as precursors for the synthesis of titanium dioxide

被引:1
作者
Evtushenko, Yu M. [1 ]
Krushevskii, G. A. [1 ]
Zaitsev, B. E. [2 ]
Romashkin, S. V. [2 ]
Davydov, V. V. [2 ]
机构
[1] ZAO Elektroizolit, Khotkovo 141371, Moscow Oblast, Russia
[2] Peoples Friendship Univ Russia, Moscow 117198, Russia
关键词
titanium ethylene glycolates; tetrabutoxytitanium; titanium dioxide; precursor; POROUS THIN-FILMS; TIO2; CONVERSION; CHEMISTRY; GLYCOL;
D O I
10.1134/S0040579510050192
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The reactions of the formation of monosubstituted titanium ethylene, diethylene, and triethylene glycolates based on the interaction of glycols with tetrabutoxytitanium in solutions were investigated. It was shown that ethylene glycol predominantly forms cyclic structures: diethylene glycol, a mixture of cyclic and linear structures, and triethylene glycol, mainly linear structures. The comparative analysis of the reaction products showed that the most promising precursor for the synthesis of TiO2 is a titanium compound based on triethylene glycol.
引用
收藏
页码:755 / 761
页数:7
相关论文
共 23 条
[1]  
BENABBOU AK, 2003, APPL CATAL B-ENVIRON, V76, P257
[2]   Synthesis of TiO2 porous thin films by polyethylene glycol templating and chemistry of the process [J].
Bu, SJ ;
Jin, ZG ;
Liu, XX ;
Yang, LR ;
Cheng, ZJ .
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2005, 25 (05) :673-679
[3]   Fabrication of TiO2 porous thin films using peg templates and chemistry of the process [J].
Bu, SJ ;
Jin, ZG ;
Liu, XX ;
Yang, LR ;
Cheng, ZJ .
MATERIALS CHEMISTRY AND PHYSICS, 2004, 88 (2-3) :273-279
[4]   Titanium dioxide nanomaterials: Synthesis, properties, modifications, and applications [J].
Chen, Xiaobo ;
Mao, Samuel S. .
CHEMICAL REVIEWS, 2007, 107 (07) :2891-2959
[5]  
EVTUSHENKO YM, Patent No. 2312324
[6]  
FILD R, 1969, ORGANICHESKAYA KHIMI
[7]  
Fujishima A., 2000, J PHOTOCHEM PHOTOB C, V1, P1, DOI DOI 10.1016/S1389-5567(00)00002-2
[8]   Dye-sensitized solar cells [J].
Grätzel, M .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY C-PHOTOCHEMISTRY REVIEWS, 2003, 4 (02) :145-153
[9]   Sol gel derived photocatalytic porous TiO2 thin films [J].
Guo, B ;
Liu, ZL ;
Hong, L ;
Jiang, HX .
SURFACE & COATINGS TECHNOLOGY, 2005, 198 (1-3) :24-29
[10]   Photocatalytic effect of the sol-gel derived nanoporous TiO2 transparent thin films [J].
Guo, B ;
Liu, ZL ;
Hong, L ;
Jiang, HX ;
Lee, JY .
THIN SOLID FILMS, 2005, 479 (1-2) :310-315