Synthesis, characterization, and cadmium(II) uptake of iminodiacetic acid-modified mesoporous SBA-15

被引:46
作者
Gao, Zhifeng
Wang, Lina
Qi, Tao [1 ]
Chu, Jinglong
Zhang, Yi
机构
[1] Chinese Acad Sci, Inst Proc Engn, Lab Green Proc & Engn, Beijing 100080, Peoples R China
[2] Grad Univ, Chinese Acad Sci, Beijing 100049, Peoples R China
基金
中国国家自然科学基金;
关键词
mesoporous SBA-15; iminodiacetic acid; characterization; cadmium; uptake;
D O I
10.1016/j.colsurfa.2007.04.045
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
An organic-inorganic hybrid mesoporous material, iminodiacetic acid (IDA)-modified mesoporous SBA-15, was prepared by a two-step post-grafting method. By means of solid-state C-13 CP-MAS NMR, thermogravimetic analysis (TGA), Fourier transform infrared (FT-IR), as well as X-ray photoelectron spectroscopy (XPS), the structural and physicochemical properties of the materials were characterized. The cadmium(II) uptake experiments show that the iminodiacetic acid-modified mesoporous SBA-15 (IDA-SBA-15) exhibits excellent ability to remove cadmium(II) from aqueous solutions. The cadmium(II) adsorption isotherm of iminodiacetic acid-modified mesoporous SBA-15 (IDA-SBA-15) is in good accordance with the Lansmuir equation. (c) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码:77 / 81
页数:5
相关论文
共 32 条
[1]   Adsorption behaviour of non-transition metal ions on a synthetic chelating resin bearing iminoacetate functions [J].
Atia, AA ;
Donia, AM ;
ELwakeel, KZ .
SEPARATION AND PURIFICATION TECHNOLOGY, 2005, 43 (01) :43-48
[2]   Synthesis of amine and thio chelating resins and study of their interaction with zinc(II), cadmium(II) and mercury(II) ions in their aqueous solutions [J].
Atia, AA ;
Donia, AM ;
Yousif, AM .
REACTIVE & FUNCTIONAL POLYMERS, 2003, 56 (01) :75-82
[3]   Functionalized silica for heavy metal ions adsorption [J].
Bois, L ;
Bonhommé, A ;
Ribes, A ;
Pais, B ;
Raffin, G ;
Tessier, F .
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2003, 221 (1-3) :221-230
[4]  
Cameron R. E., 1992, GUIDE SITE SOIL DESC, V1
[5]   Adsorptions of heavy metal ions by a magnetic chelating resin containing hydroxy and iminodiacetate groups [J].
Chen, Chuh-Yean ;
Chiang, Chen-Li ;
Huang, Po-Chen .
SEPARATION AND PURIFICATION TECHNOLOGY, 2006, 50 (01) :15-21
[6]   Functionalization of SBA-15 with APTES and characterization of functionalized materials [J].
Chong, ASM ;
Zhao, XS .
JOURNAL OF PHYSICAL CHEMISTRY B, 2003, 107 (46) :12650-12657
[7]   Heavy metals uptake by Sardinian natural zeolites:: Experiment and modeling [J].
Cincotti, A ;
Mameli, A ;
Locci, AM ;
Orrù, R ;
Cao, G .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2006, 45 (03) :1074-1084
[8]   Removal of cadmium, zinc, manganese and chromium cations from aqueous solution by a clay mineral [J].
da Fonseca, Maria G. ;
de Oliveira, Michelle M. ;
Arakaki, Luiza N. H. .
JOURNAL OF HAZARDOUS MATERIALS, 2006, 137 (01) :288-292
[9]   Comparison of three Mexican aluminosilicates for the sorption of cadmium [J].
Dávila-Rangel, JI ;
Solache-Ríos, M ;
Badillo-Almaraz, VE .
JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY, 2005, 267 (01) :139-145
[10]   Adsorption of Cu(II), Zn(II), Ni(II), Pb(II), and Cd(II) from aqueous solution on amberlite IR-120 synthetic resin [J].
Demirbas, A ;
Pehlivan, E ;
Gode, F ;
Altun, T ;
Arslan, G .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2005, 282 (01) :20-25