Removal of phenolic pollutants from wastewater streams using ionic liquids

被引:63
作者
Sas, Olalla G. [1 ]
Sanchez, Pablo B. [2 ]
Gonzalez, Begona [1 ]
Dominguez, Angeles [1 ]
机构
[1] Dept Chem Engn, Adv Separat Proc Grp, Vigo, Spain
[2] Univ Vigo, Dept Fis Aplicada, Vigo, Spain
关键词
Phenolic pollutants; Ionic liquids; Extraction; Molecular dynamics; Green chemistry; FORCE-FIELD; EXTRACTION; BEHAVIOR; CHLOROPHENOLS; IMIDAZOLIUM;
D O I
10.1016/j.seppur.2019.116310
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The removal of toxic phenolic compounds from wastewater streams with ionic liquids as extracting agents have been addressed with experiments and simulations. Three phenolic compounds, phenol, chlorophenol and o-cresol, were extracted from aqueous streams at different concentrations using five ionic liquids allowing to study the effect of both ionic structures, the anion and the cation, on the extraction efficiency. Besides, the interactions between phenols and ions were analysed by means of atomistic molecular dynamic simulations and their solvation environment described. Finally, the accomplishment of the regulations regarding phenol concentrations in wastewater streams was discussed.
引用
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页数:6
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