Highly flexible transparent film heaters based on random networks of silver nanowires

被引:271
作者
Celle, Caroline [1 ]
Mayousse, Celine [1 ]
Moreau, Eleonore [1 ]
Basti, Henda [1 ]
Carella, Alexandre [1 ]
Simonato, Jean-Pierre [1 ]
机构
[1] LITEN DTNM LCRE, CEA, F-38054 Grenoble, France
关键词
Thin film heater; silver nanowires; transparent; electrode; flexible; thermochromic display; WALLED CARBON NANOTUBES; SOLAR-CELLS; ELECTRODES; POLYMER;
D O I
10.1007/s12274-012-0225-2
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We demonstrate a new concept for the fabrication of flexible transparent thin film heaters based on silver nanowires. Thanks to the intrinsic properties of random networks of metallic nanowires, it is possible to combine bendability, transparency and high heating performances at low voltage, typically below 12 V which is of interest for many applications. This is currently not possible with transparent conductive oxide technologies, and it compares well with similar devices fabricated with carbon nanotubes or graphene. We present experiments on glass and poly(ethylene naphthalate) (PEN) substrates (with thicknesses of 125 mu m and extremely thin 1.3 mu m) with excellent heating performances. We point out that the amount of silver necessary to realize the transparent heaters is very low and we also present preliminary results showing that this material can be efficiently used to fabricate photochromic displays. To our knowledge, this is the first report of metallic nanowire-based transparent thin film heaters. We think these results could be a useful approach for the engineering of highly flexible and transparent heaters which are not attainable by existing processes.
引用
收藏
页码:427 / 433
页数:7
相关论文
共 28 条
[1]   Electrical sintering of nanoparticle structures [J].
Allen, Mark L. ;
Aronniemi, Mikko ;
Mattila, Tomi ;
Alastalo, Ari ;
Ojanpera, Kimmo ;
Suhonen, Mika ;
Seppa, Heikki .
NANOTECHNOLOGY, 2008, 19 (17)
[2]   Size Effects and the Problem with Percolation in Nanostructured Transparent Conductors [J].
De, Sukanta ;
King, Paul J. ;
Lyons, Philip E. ;
Khan, Umar ;
Coleman, Jonathan N. .
ACS NANO, 2010, 4 (12) :7064-7072
[3]   Smooth Nanowire/Polymer Composite Transparent Electrodes [J].
Gaynor, Whitney ;
Burkhard, George F. ;
McGehee, Michael D. ;
Peumans, Peter .
ADVANCED MATERIALS, 2011, 23 (26) :2905-2910
[4]   Emerging Transparent Electrodes Based on Thin Films of Carbon Nanotubes, Graphene, and Metallic Nanostructures [J].
Hecht, David S. ;
Hu, Liangbing ;
Irvin, Glen .
ADVANCED MATERIALS, 2011, 23 (13) :1482-1513
[5]   Metal nanogrids, nanowires, and nanofibers for transparent electrodes [J].
Hu, Liangbing ;
Wu, Hui ;
Cui, Yi .
MRS BULLETIN, 2011, 36 (10) :760-765
[6]   Scalable Coating and Properties of Transparent, Flexible, Silver Nanowire Electrodes [J].
Hu, Liangbing ;
Kim, Han Sun ;
Lee, Jung-Yong ;
Peumans, Peter ;
Cui, Yi .
ACS NANO, 2010, 4 (05) :2955-2963
[7]   The manufacture of a transparent film heater by spinning multi-walled carbon nanotubes [J].
Jang, Hoon-Sik ;
Jeon, Sang Koo ;
Nahm, Seung Hoon .
CARBON, 2011, 49 (01) :111-116
[8]   High-Performance Graphene-Based Transparent Flexible Heaters [J].
Kang, Junmo ;
Kim, Hyeongkeun ;
Kim, Keun Soo ;
Lee, Seoung-Ki ;
Bae, Sukang ;
Ahn, Jong-Hyun ;
Kim, Young-Jin ;
Choi, Jae-Boong ;
Hong, Byung Hee .
NANO LETTERS, 2011, 11 (12) :5154-5158
[9]   Thickness-dependent thermal resistance of a transparent glass heater with a single-walled carbon nanotube coating [J].
Kang, Tae June ;
Kim, Taewoo ;
Seo, Sung Min ;
Park, Young June ;
Kim, Yong Hyup .
CARBON, 2011, 49 (04) :1087-1093
[10]   Thermal Behavior of Transparent Film Heaters Made of Single-Walled Carbon Nanotubes [J].
Kim, Duckjong ;
Lee, Hyun-Chang ;
Woo, Ju Yeon ;
Han, Chang-Soo .
JOURNAL OF PHYSICAL CHEMISTRY C, 2010, 114 (13) :5817-5821