Hexadecacobalt(II)-Containing Polyoxometalate-Based Single-Molecule Magnet

被引：250
|
作者：
Ibrahim, Masooma [2 ,3 ]
Lan, Yanhua [1 ]
Bassil, Bassem S. [2 ]
Xiang, Yixian [2 ]
Suchopar, Andreas [2 ]
Powell, Annie K. [1 ]
Kortz, Ulrich [2 ]
机构：
[1] KIT, Inst Anorgan Chem, D-76131 Karlsruhe, Germany
[2] Jacobs Univ, Sch Sci & Engn, D-28725 Bremen, Germany
[3] Univ Balochistan, Quetta 87300, Pakistan
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 20期
关键词：
cobalt; inorganic synthesis; multinuclear complexes; polyoxometalates; single-molecule magnets; CRYSTAL-STRUCTURE; TRANSITION-METAL; COBALT; CLUSTERS; MANGANESE; FAMILY; TUNGSTOPHOSPHATE; DERIVATIVES; NUCLEARITY; CHEMISTRY;
D O I：
10.1002/anie.201100280
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
POMs, magnets, and Co: The tetrameric 36-tungsto-8-phosphate [{Co 4(OH)3PO4}4(PW9O 34)4]28- containing 16 cobalt(II) centers was prepared by a simple, one-pot synthetic procedure. The {Co16(OH) 12(PO4)4}8+ core (see picture) exhibits single-molecule magnetic behavior. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：4708 / 4711
页数：4
相关论文
共 50 条
  • [1] Polyoxometalate-based single-molecule magnets
    Fang, Xikui
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2011, 242
  • [2] A polyoxometalate-based single-molecule magnet with an S=21/2 ground state
    Fang, Xikui
    Koegerler, Paul
    Speldrich, Manfred
    Schilder, Helmut
    Luban, Marshall
    CHEMICAL COMMUNICATIONS, 2012, 48 (09) : 1218 - 1220
  • [3] Organophosphonate-Bridged Polyoxometalate-Based Dysprosium(III) Single-Molecule Magnet
    Huo, Yu
    Wan, Rong
    Ma, Pengtao
    Liu, Junliang
    Chen, Yancong
    Li, Dandan
    Niu, Jingyang
    Wang, Jingping
    Tong, Ming-Liang
    INORGANIC CHEMISTRY, 2017, 56 (21) : 12687 - 12691
  • [4] Single-molecule magnets within polyoxometalate-based frameworks
    Zarch, Malihe Babaei
    Mirzaei, Masoud
    Bazargan, Maryam
    Gupta, Sandeep K.
    Meyer, Franc
    Mague, Joel T.
    DALTON TRANSACTIONS, 2021, 50 (42) : 15047 - 15056
  • [5] Recent advances in polyoxometalate-based single-molecule magnets
    Yang, Zeng-Xi
    Gong, Feng
    Lin, Dunmin
    Huo, Yu
    COORDINATION CHEMISTRY REVIEWS, 2023, 492
  • [6] Two polyoxometalate-based hybrids constructed from trinuclear lanthanoid clusters with single-molecule magnet behavior
    Khoshkhan, Zakiyeh
    Mirzaei, Masoud
    Eshtiagh-Hosseini, Hossein
    Izadyar, Mohammad
    Mague, Joel T.
    Korabik, Maria
    POLYHEDRON, 2021, 194
  • [7] Polyoxometalate-based {Mn2III}-Schiff base composite materials exhibiting single-molecule magnet behaviour
    Wu, Qiong
    Li, Yang-Guang
    Wang, Yong-Hui
    Clerac, Rodolphe
    Lu, Ying
    Wang, En-Bo
    CHEMICAL COMMUNICATIONS, 2009, (38) : 5743 - 5745
  • [8] A Stable Hybrid Bisphosphonate Polyoxometalate Single-Molecule Magnet
    El Moll, Hani
    Dolbecq, Anne
    Marrot, Jerome
    Rousseau, Guillaume
    Haouas, Mohamed
    Taulelle, Francis
    Rogez, Guillaume
    Wernsdorfer, Wolfgang
    Keita, Bineta
    Mialane, Pierre
    CHEMISTRY-A EUROPEAN JOURNAL, 2012, 18 (13) : 3845 - 3849
  • [9] A polyoxometalate-based single-molecule magnet with a mixed-valent {MnIV2MnIII6MnII4} core
    Zhang, Zhi-Ming
    Yao, Shuang
    Li, Yang-Guang
    Wu, Hai-Hong
    Wang, Yong-Hui
    Rouzieres, Mathieu
    Clerac, Rodolphe
    Su, Zhong-Min
    Wang, En-Bo
    CHEMICAL COMMUNICATIONS, 2013, 49 (25) : 2515 - 2517
  • [10] A nonanuclear iron(II) single-molecule magnet
    Boudalis, AK
    Donnadieu, B
    Nastopoulos, V
    Clemente-Juan, JM
    Mari, A
    Sanakis, Y
    Tuchagues, JP
    Perlepes, SP
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (17) : 2266 - 2270
12345