Novel complexes of Mn(III) with macrocylic porphine ligand and ethylenediamine

被引：13

作者：

Yadava, Sudha ^{[1
]}

Bharati, Shashi Lata ^{[1
]}

机构：

[1] DDU Gorakhpur Univ, Dept Chem, Gorakhpur 273009, Uttar Pradesh, India

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2011年 / 64卷 / 22期

关键词：

Tetra-p-methoxyphenylporphine; Ethylenediamine; Mn(III) porphyrins; Spectroscopic studies; MANGANESE PORPHYRINS; INFRARED-SPECTRA; WATER; STEREOCHEMISTRY; 5-COORDINATE; ABSORPTION; CRYSTAL; SENSORS; SERIES;

D O I：

10.1080/00958972.2011.632412

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The present work describes the synthesis and characterization of a few Mn(III) porphyrins with ethylenediamine. A new series of high-spin Mn(III) porphyrins having general formula [Mn(TMPP) X] and [Mn(TMPP) X(en)], where TMPP = tetra-p-methoxyphenylporphinato ligand, X = Cl-, Br-, N-3(-) or NCS- and en ethylenediamine. Molar conductance values of these complexes show their non-electrolytes in ethyl alcohol. These complexes have been characterized by U.V., I.R., ESI-mass spectra, elemental analyses and magnetic susceptibility measurements. The tentative structures have also been proposed.

引用

页码：3950 / 3959

页数：10

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