Synthesis, spectral characterization and biological activity of zinc(II) complexes with 3-substituted phenyl-4-amino-5-hydrazino-1, 2, 4-triazole Schiff bases

被引:0
作者
Singh, A. K. [1 ]
Pandey, O. P. [1 ]
Sengupta, S. K. [1 ]
机构
[1] DDU Gorakhpur Univ, Dept Chem, Gorakhpur 273009, Uttar Pradesh, India
关键词
Zn(II); Schiff bases; FT-IR; H-1; NMR; C-13; Antifungal and antibacterial; ZN(II) COMPLEXES; MANNICH-BASES; CU(II); NI(II); CO(II); ANTIBACTERIAL; DERIVATIVES; ANTIFUNGAL;
D O I
10.1016/j.saa.2011.08.019
中图分类号
O433 [光谱学];
学科分类号
0703 ; 070302 ;
摘要
New Zn(II) complexes have been synthesized by the reactions of zinc(II) acetate with Schiff bases derived from 3-substituted phenyl-4-amino-5-hydrazino-1, 2, 4-triazole and benzaldehyde, 2-hydroxyacetophenone or indoline-2,3-dione. All these complexes are soluble in DMF and DMSO; low molar conductance values indicate that they are non-electrolytes. Elemental analyses suggest that the complexes have 1:1 stoichiometry of the type [ZnL(H2O)(2)], [ZnL'(OAc)(2)(H2O)(2)](L=dianionic Schiff bases derived from 3-(substituted phenyl)-4-amino-5-hydrazino-1, 2, 4-triazole and 2-hydroxyacetophenone or indoline-2,3-dione; L' = neutral Schiff bases derived from 3-(substituted pheny)-4-amino-5-hydrazino-1, 2, 4-triazole and benzaldehyde) and they were characterized by FT-IR, H-1 NMR, C-13 NMR and FAB mass. All these Schiff bases and their complexes have also been screened for their antibacterial activities against Bacillus subtilis,Escherichia coli and antifungal activities against Colletotrichum falcatum, Aspergillus niger, Fusarium oxysporium and Carvularia pallescence by petriplates methods. (C) 2011 Published by Elsevier B.V.
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页码:1 / 6
页数:6
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