First concise total synthesis of 5-epi-prelactone B

被引:11
|
作者
Srihari, P. [1 ]
Ravindar, K. [1 ]
Somaiah, R. [1 ]
Yadav, J. S. [1 ]
机构
[1] Indian Inst Chem Technol, Organ Div 1, Hyderabad 500007, Andhra Pradesh, India
关键词
aldol; delta-lactones; prelactone B; sharpless asymmetric epoxidation; Wittig reaction;
D O I
10.1080/00397910801914194
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
First short total synthesis of 5-epi-prelactone B has been achieved involving Sharpless asymmetric epoxidation and intramolecular hydride transfer reaction for formation of the aldol product by nonaldol chemistry as the key steps.
引用
收藏
页码:1389 / 1397
页数:9
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