Reaction between triphenylphosphine and aromatic amines in the presence of diethyl azodicarboxylate: an efficient synthesis of aryliminophosphoranes under neutral and mild conditions

被引：15
作者：
Adib, Mehdi [1 ]
Sheikhi, Ehsan [1 ]
Deljoush, Azadeh [1 ]
机构：
[1] Univ Tehran, Univ Coll Sci, Sch Chem, Tehran, Iran
来源：
TETRAHEDRON | 2011年 / 67卷 / 22期
关键词：
Aryliminophosphoranes; Triphenylphosphine; Diethyl azodicarboxylate; Mitsonobu reaction; AZA-WITTIG REACTION; ONE-POT; HUISGEN ZWITTERION; MITSUNOBU REACTION; CARBONYL-COMPOUNDS; DERIVATIVES; PHOSPHINE; ACID; DIARYL-1,2-DIONES; IMINOPHOSPHORANES;
D O I：
10.1016/j.tet.2011.03.097
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
An efficient synthesis of aryliminophosphoranes is described. A mixture of an aromatic amine, diethyl azodicarboxylate and triphenylphosphine undergo a Mitsonobu type reaction at ambient temperature in dry dichloromethane to afford aryliminophosphoranes in excellent yields. (C) 2011 Elsevier Ltd. All rights reserved.
引用
收藏
页码：4137 / 4140
页数：4
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