Hydrothermal synthesis and crystal structure of a novel two-dimensional molybdenum(V) phosphate with manganese coordination cations

被引：8
作者：
Wu, Dan [1 ,2 ]
Lin, Shen [1 ,3 ]
Tang, En [3 ]
Yan, Guiyang [1 ]
机构：
[1] Fujian Normal Univ, Coll Chem & Mat Sci, Fuzhou 35007, Peoples R China
[2] Fujian Agr & Forest Univ, Coll Biol Sci, Fuzhou 35002, Peoples R China
[3] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China
来源：
COMPTES RENDUS CHIMIE | 2008年 / 11卷 / 1-2期
关键词：
molybdenum(V) phosphate; hydrothermal synthesis; two-dimensional network; inorganic-organic hybrid; manganese;
D O I：
10.1016/j.crci.2007.03.008
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A novel two-dimensional network structure formed by molybdenum(V) phosphate and manganese coordination cations, [Mn2Mo12O30(HPO4)(8)(H2O)]center dot(NH3CH2CH2NH3)(6)center dot 3.5H(2)O (1), was synthesized hydrothermally and characterized by single-crystal X-ray diffraction. It crystallizes in the triclinic system, space group P (1) over bar, with a = 12.006(2) angstrom, b = 14.582(3) angstrom, c = 21.270(4) angstrom, alpha = 86.00(3)degrees, beta = 88.00(3)degrees, gamma = 78.00(3)degrees, the final R converged to the value 0.0604 for 12 917 observed reflections with I > 2 sigma(I). In this compound, the poly(oxomolybdophosphate) anions are interconnected by transition-metal manganese cations to form an extended two-dimensional framework where the uncoordinated ethylenediamine cations and lattice water molecules are located.
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页码：152 / 158
页数：7
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