A two-dimensional clathrate hydrate sandwiched by planar arrays of a copper complex

被引：32

作者：

Miyamoto, R

Hamazawa, RT

Hirotsu, M

Nishioka, T

Kinoshita, I

Wright, LJ

机构：

[1] Osaka City Univ, Dept Mol Mat Sci, Osaka 5588585, Japan

[2] Univ Auckland, Dept Chem, Auckland 1020, New Zealand

来源：

CHEMICAL COMMUNICATIONS | 2005年 / 32期

关键词：

D O I：

10.1039/b505681k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first structurally characterised example of a 2-D clathrate hydrate spontaneously assembles when CuF(tptm)] (1) (tptm = tris(2-pyridylthio)methyl) crystallises from toluene/ water solutions to produce a material in which planar arrays of [CuF(tptm)] sandwich and hydrogen bond to continuous 2-D sheets of water that incorporate toluene molecules at regular intervals.

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收藏

页码：4047 / 4049

页数：3

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