Amino Acids as Raw Material for Biocompatible Surfactants

被引:133
作者
Pinazo, Aurora [1 ]
Pons, Ramon [1 ]
Perez, Lourdes [1 ]
Rosa Infante, Maria [1 ]
机构
[1] CSIC Barcelona, Inst Quim Avancada Catalunya, Barcelona, Spain
关键词
ARGININE-BASED SURFACTANTS; ALKANEDIYL-ALPHA; OMEGA-BIS(DIMETHYLALKYLAMMONIUM BROMIDE) SURFACTANTS; CATIONIC AMPHIPHILIC COMPOUNDS; CHAIN-LENGTH; BIOLOGICAL-PROPERTIES; NONCONVENTIONAL SURFACTANTS; CHEMOENZYMATIC SYNTHESIS; AQUEOUS-SOLUTIONS; MOLECULAR MIMICS; WATER;
D O I
10.1021/ie1014348
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Surfactants are chemical products consumed in large quantities every day on a worldwide scale. The development of less irritant, less toxic, consumer-friendly surfactants is, therefore, of general interest. Amino-acid-based surfactants constitute a novel class of surfactants produced from renewable raw materials and can be seen as an alternative to conventional surfactants. With the aim of testing their applicability in formulations for pharmaceutical, food, and cosmetic industries we have carried out exhaustive studies to elucidate their properties as surfactants. We considered amino acid-based surfactants with one single chain, cystine or arginine gemini surfactants, lysine derivatives, and surfactants with glycerolipid-like structure.
引用
收藏
页码:4805 / 4817
页数:13
相关论文
共 99 条
[61]  
2-N
[62]   Comparative evaluation of cytotoxicity and phototoxicity of mono and diacylglycerol amino acid-based surfactants [J].
Pilar Vinardell, Maria ;
Benavides, Tomas ;
Mitjans, Montserrat ;
Rosa Infante, Maria ;
Clapes, Pere ;
Clothier, Richard .
FOOD AND CHEMICAL TOXICOLOGY, 2008, 46 (12) :3837-3841
[63]   Aggregation properties of diacyl lysine surfactant compounds:: Hydrophobic chain length and counterion effect [J].
Pinazo, A. ;
Perez, L. ;
Lozano, M. ;
Angelet, M. ;
Infante, M. R. ;
Vinardell, M. P. ;
Pons, R. .
JOURNAL OF PHYSICAL CHEMISTRY B, 2008, 112 (29) :8578-8585
[64]   Aggregation behavior in water of monomeric and gemini cationic surfactants derived from arginine [J].
Pinazo, A ;
Wen, XY ;
Pérez, L ;
Infante, MR ;
Franses, EI .
LANGMUIR, 1999, 15 (09) :3134-3142
[65]   Unconventional vesicle-to-ribbon transition behaviour of diacyl glycerol amino acid based surfactants in extremely diluted systems induced by pH-concentration effects [J].
Pinazo, A ;
Pérez, L ;
Infante, MR ;
Pons, R .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2004, 6 (07) :1475-1481
[66]   SURFACE-TENSION PROPERTIES OF AQUEOUS-SOLUTIONS OF DISULFUR BETAINE DERIVATIVES [J].
PINAZO, A ;
INFANTE, MR ;
CHANG, CH ;
FRANSES, EI .
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 1994, 87 (02) :117-123
[67]   Surface properties of aqueous systems of new nonionic double-chain surfactants and their mixtures with dilauroylphosphatidylcholine [J].
Pinazo, A ;
Seguer, J ;
Infante, MR ;
Park, SY ;
Franses, EI .
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 1997, 126 (01) :49-58
[68]   Relation of foam stability to solution and surface properties of gemini cationic surfactants derived from arginine [J].
Pinazo, A ;
Pérez, L ;
Infante, MR ;
Franses, EI .
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2001, 189 (1-3) :225-235
[69]   DYNAMIC SURFACE-TENSION BEHAVIOR OF AQUEOUS-SOLUTIONS OF N-DODECYL-N,N DIMETHYL AMINOBETAINE CHLORHYDRATE [J].
PINAZO, A ;
CHANG, CH ;
FRANSES, EI .
COLLOID AND POLYMER SCIENCE, 1994, 272 (04) :447-455
[70]   Synthesis of arginine-based surfactants in highly concentrated water-in-oil emulsions [J].
Pinazo, A ;
Infante, MR ;
Izquierdo, P ;
Solans, C .
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 2000, (07) :1535-1539