New synthesis of polyfluoroalkanesulfonylureas

被引:11
作者
Benfodda, Z.
Delon, L.
Guillen, E.
Blancou, H.
机构
[1] Univ Montpellier 1, CNRS, IBMM, UMR 5247, F-34095 Montpellier 05, France
[2] Univ Montpellier 2, CNRS, IBMM, UMR 5247, F-34095 Montpellier, France
关键词
F-alkanesulfonyl ureas; sodium salt of perfluorcalkane sulfonamide; isocyanates;
D O I
10.1016/j.jfluchem.2007.05.022
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
This study describes a new synthesis of F-alkanesulfonyl ureas by reaction of the sodium salt of perfluoroalkane sulfonamide (R-F = C4F9, C6F13) with some isocyanates in anhydrous THE The perfluorinated sulfonylureas are obtained, in one step, from moderate to good yields. (c) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码:1353 / 1358
页数:6
相关论文
共 16 条
[1]  
Banks R.E., 1994, ORGANOFLUORINE CHEM
[2]   PSEUDOHALIDE COMPOUNDS .20. PERFLUORINATED ALKANESULFONYL PSEUDOHALIDES AND PHENYLSULFONYLPSEUDOHALIDES [J].
BEHREND, E ;
HAAS, A .
JOURNAL OF FLUORINE CHEMISTRY, 1974, 4 (01) :83-98
[3]   DESCRIPTION OF A PROCESS OF CATALYTIC PREPARATION OF PERFLUOROALKYL SULFONAMIDE BY THE ADDITION OF ETHYLAMINE TO A PERFLUOROALKYLSULFONIC ACID CHLORIDE [J].
BENEFICEMALOUET, S ;
BLANCOU, H ;
TEISSEDRE, R ;
COMMEYRAS, A .
JOURNAL OF FLUORINE CHEMISTRY, 1986, 31 (03) :319-332
[4]  
BLANCOU H, 2002, Patent No. 2002081081
[5]  
BLANCOU H, 2002, Patent No. 2002081431
[6]  
BROWN HM, 1994, CHEM PLANT PROT, V10, P47
[7]   Sulfonylureas in the therapy of type 2 diabetes mellitus: where do we stand today? [J].
Del Prato, S .
METABOLISM-CLINICAL AND EXPERIMENTAL, 2006, 55 (05) :S1-S1
[8]   Pharmacological agents that directly modulate insulin secretion [J].
Doyle, ME ;
Egan, JM .
PHARMACOLOGICAL REVIEWS, 2003, 55 (01) :105-131
[9]  
GERSTENBERGER MRC, 1982, HELV CHIM ACTA, V65, P490, DOI 10.1002/hlca.19820650207
[10]   CHEMISTRY OF SULFONYLUREA HERBICIDES [J].
HAY, JV .
PESTICIDE SCIENCE, 1990, 29 (03) :247-261