Synthesis, characterization and catalytic activity of Fe(III) complexes containing Schiff base and triphenylphosphine ligands

被引：2

作者：

Rani, Sandya ^{[1
]}

Bhat, Badekai Ramachandra ^{[1
]}

机构：

[1] Natl Inst Technol Karnataka, Catalysis & Mat Chem Div, Dept Chem, Srinivasnagar 575025, Karnataka, India

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2010年 / 13卷 / 11期

关键词：

Fe(III) complexes; Schiff base; Triphenylphosphine; Oxidation of alcohol; CRYSTAL-STRUCTURE; IRON(III); OXIDATION; NICKEL(II); ALCOHOLS; COPPER;

D O I：

10.1016/j.inoche.2010.07.018

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The oxidation of alcohols to carbonyls was investigated by an efficient catalyst system comprising of Fe(III)-Schiff base-triphenylphosphine complex. The complex chloroN-(2-mercaptophenyl)salicylideneiminebis (triphenylphosphine)iron(III) showed higher activity for oxidation of various alcohols under relatively mild conditions. (C) 2010 Elsevier B.V. All rights reserved.

引用

页码：1289 / 1292

页数：4

共 27 条

[1] Synthesis and characterization of iron(III), manganese(II), cobalt(II), nickel(II), copper(II) and zinc(II) complexes of salicylidene-N-anilinoacetohydrazone (H2L1) and 2-hydroxy-1-naphthylidene-N-anilinoacetohydrazone (H2L2) [J].

AbouEl-Enein, S. A. ;

El-Saied, F. A. ;

Kasher, T. I. ;

El-Wardany, A. H. .

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2007, 67 (3-4) :737-743

[2]

Albin L.D., 1995, US Patent, Patent No. [5,426,085, 5426085]

[3] Synthesis, characterization and catalytic activity of dinuclear iron(III) and ruthenium(III) complexes [J].

Aneetha, H ;

Padmaja, J ;

Zacharias, PS .

POLYHEDRON, 1996, 15 (14) :2445-2451

[4] Synthesis, X-ray structure and study of a mixed ligand iron(III) complex with tridentate Schiff base as a homogeneous catalyst in the efficient oxidation of sulfides [J].

Bagherzadeh, Mojtaba ;

Tahsini, Laleh ;

Latifi, Reza ;

Amani, Vahid ;

Ellern, Arkady ;

Woo, L. Keith .

INORGANIC CHEMISTRY COMMUNICATIONS, 2009, 12 (06) :476-480

[5] Synthesis, characterization, catalytic, electrochemical and thermal properties of tetradentate Schiff base complexes [J].

Deligonul, Nihal ;

Tumer, Mehmet ;

Serin, Selahattin .

TRANSITION METAL CHEMISTRY, 2006, 31 (07) :920-929

[6] Synthesis, structure and catalytic activity of new chiral nitrogen-containing ligands [J].

Fonseca, MH ;

Eibler, E ;

Zabel, M ;

König, B .

INORGANICA CHIMICA ACTA, 2003, 352 :136-142

[7] The synthesis, characterization, electrochemical character, catalytic and antimicrobial activity of novel, azo-containing Schiff bases and their metal complexes [J].

Ispir, Esin .

DYES AND PIGMENTS, 2009, 82 (01) :13-19

[8]

KALRA SJS, 1994, TETRAHEDRON LETT, V35, P4847

[9] Synthesis, characterization, catalytic oxidation and biological activity of ruthenium(III) Schiff base complexes derived from 3-acetyl-6-methyl-2H-pyran-2,4(3H)-dione [J].

Kannan, Sethuraman ;

Ramesh, Rengan .

POLYHEDRON, 2006, 25 (16) :3095-3103

[10]

Latif S.A.A., 2007, SPECTROCHIM ACTA A, V67, P950

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