Synthesis, characterization and catalytic activity of Fe(III) complexes containing Schiff base and triphenylphosphine ligands

被引:2
作者
Rani, Sandya [1 ]
Bhat, Badekai Ramachandra [1 ]
机构
[1] Natl Inst Technol Karnataka, Catalysis & Mat Chem Div, Dept Chem, Srinivasnagar 575025, Karnataka, India
关键词
Fe(III) complexes; Schiff base; Triphenylphosphine; Oxidation of alcohol; CRYSTAL-STRUCTURE; IRON(III); OXIDATION; NICKEL(II); ALCOHOLS; COPPER;
D O I
10.1016/j.inoche.2010.07.018
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The oxidation of alcohols to carbonyls was investigated by an efficient catalyst system comprising of Fe(III)-Schiff base-triphenylphosphine complex. The complex chloroN-(2-mercaptophenyl)salicylideneiminebis (triphenylphosphine)iron(III) showed higher activity for oxidation of various alcohols under relatively mild conditions. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码:1289 / 1292
页数:4
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