Synthesis of silicon-substituted tricyclononenes

被引：19

作者：

Bermeshev, M. V. ^{[1
]}

Syromolotov, A. V. ^{[1
]}

Gringolts, M. L. ^{[1
]}

Lakhtin, V. G. ^{[2
]}

Finkelshtein, E. Sh. ^{[1
]}

机构：

[1] AV Topchiev Petrochem Synth Inst, Moscow 119991, Russia

[2] State Res Inst Chem & Technol Organoelement Cpds, State Sci Ctr Russian Federat, Moscow 111123, Russia

来源：

TETRAHEDRON LETTERS | 2011年 / 52卷 / 46期

关键词：

Tricyclononenes; Norbornene derivatives; Silicon-containing monomers; CYCLOADDITION REACTIONS; QUADRICYCLANE; POLYMERIZATION; ACETYLENE; POLYMERS; ETHYLENE;

D O I：

10.1016/j.tetlet.2011.09.009

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new series of tricyclononene derivatives with two and three silyl groups are successfully synthesized via [2 sigma+2 sigma+2 pi]-cycloaddition of silylethylenes to quadricyclane. The activity of the silylethylenes in the cycloaddition reactions was estimated. (C) 2011 Elsevier Ltd. All rights reserved.

引用

页码：6091 / 6093

页数：3

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