Recent advances in visible-light photoredox-catalyzed nitrogen radical cyclization

被引：97

作者：

Wang, Pengzi ^{[1
]}

Zhao, Quanqing ^{[1
]}

Xiao, Wenjing ^{[1
,2
]}

Chen, Jiarong ^{[1
]}

机构：

[1] Cent China Normal Univ, Coll Chem, CCNU uOttawa Joint Res Ctr, Key Lab Pesticides & Chem Biol,Minist Educ, Wuhan 430079, Peoples R China

[2] Shanghai Inst Organ Chem, State Key Lab Organomet Chem, Shanghai 200032, Peoples R China

来源：

GREEN SYNTHESIS AND CATALYSIS | 2020年 / 1卷 / 01期

基金：

中国国家自然科学基金;

关键词：

Photoredox catalysis; Nitrogen radicals; Radical cyclization reactions; Nitrogen-containing compounds; Nitrogen heterocycles; INTERMOLECULAR 3+2 ANNULATION; IMINYL RADICALS; CENTERED RADICALS; ELECTRON-TRANSFER; RECENT PROGRESS; CASCADE; AMINATION; BOND; HYDROAMINATION; GENERATION;

D O I：

10.1016/j.gresc.2020.05.003

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Visible-light photoredox catalysis is a powerful and attractive strategy for organic molecule activation and new reaction design owing to its environmental-friendly characteristics and unique catalytic mechanisms, and has found wide applications in organic synthesis. This catalytic strategy enables controllable generation of diverse nitrogen-centered radicals (NCRs) under mild conditions, providing access to construction of diverse nitrogencontaining compounds. In this review, we critically illustrate the recent advances in the field of visible-light photoredox-catalyzed cyclization of nitrogen-centered radicals, based on the different radical precursors and activation modes. Wherever possible, particular emphasis is also put on working models and synthetic applications.

引用

页码：42 / 51

页数：10

共 86 条

[1] Visible-Light-Promoted and One-Pot Synthesis of Phenanthridines and Quinolines from Aldehydes and O-Acyl Hydroxylamine [J].