Moisture diffusion and its impact on uniaxial tensile response of biobased composites

被引:47
作者
Christian, S. J. [2 ]
Billington, S. L. [1 ]
机构
[1] Stanford Univ, Dept Civil & Environm Engn, Stanford, CA 94305 USA
[2] Carnegie Mellon Univ, Dept Civil & Environm Engn, Pittsburgh, PA 15213 USA
关键词
Fabrics/textiles; Laminates; Environmental degradation; Mechanical properties; Biobased; WATER-ABSORPTION;
D O I
10.1016/j.compositesb.2011.11.063
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Biobased composites made from biopolymers and plant-based fibers are being evaluated for construction applications as replacements for wood or petroleum-based composites and plastics. The biobased composites studied here have been demonstrated to rapidly biodegrade in anaerobic conditions to methane thereby reducing construction-related landfill waste and producing a useful end product, namely fuel for energy or a feedstock to grow more biopolymer. To be a useful in construction, susceptibility to moisture and eventual moisture resistance is necessary. Diffusion properties and mechanical properties are characterized in various moisture and temperature conditions for hemp/cellulose acetate and hemp/poly(beta-hydroxybutyrate) composites. The composites were observed to follow Fick's 2nd law of diffusion. The tensile moduli of elasticity were found to decrease with full moisture saturation while the ductility increased and the ultimate strength did not change significantly. Measured diffusion coefficients are compared to petroleum-based and other biobased composites. (C) 2011 Elsevier Ltd. All rights reserved.
引用
收藏
页码:2303 / 2312
页数:10
相关论文
共 29 条
[1]   Comparative study of water absorption behavior in Biopo® and jute-reinforced Biopol® composite using neutron radiography technique [J].
Alam, M. K. ;
Khan, M. A. ;
Lehmann, E. H. .
JOURNAL OF REINFORCED PLASTICS AND COMPOSITES, 2006, 25 (11) :1179-1187
[2]   Effect of water sorption on the flexural properties of a fully biodegradable composite [J].
Alvarez, VA ;
Vázquez, A .
JOURNAL OF COMPOSITE MATERIALS, 2004, 38 (13) :1165-1182
[3]   Effects of the moisture and fiber content on the mechanical properties of biodegradable polymer-sisal fiber biocomposites [J].
Alvarez, VA ;
Fraga, AN ;
Vázquez, A .
JOURNAL OF APPLIED POLYMER SCIENCE, 2004, 91 (06) :4007-4016
[4]  
[Anonymous], 2010, Standard Test Methods for Flexural Properties of Unreinforced and Reinforced Plastics and Electrical Insulating Materials, P1
[5]  
Augl JM, 1976, 767 NSWCWOLTR
[6]   CELLULOSE-ACETATE BUTYRATE AND POLY(HYDROXYBUTYRATE-CO-VALERATE) COPOLYMER BLENDS [J].
BUCHANAN, CM ;
GEDON, SC ;
WHITE, AW ;
WOOD, MD .
MACROMOLECULES, 1992, 25 (26) :7373-7381
[7]   Recycled milk pouch and virgin low-density Polyethylene/Linear low-density polyethylene based coir fiber composites [J].
Choudhury, Arup ;
Kumar, Sandeep ;
Adhikari, Basudarn .
JOURNAL OF APPLIED POLYMER SCIENCE, 2007, 106 (02) :775-785
[8]   Mechanical response of PHB- and cellulose acetate natural fiber-reinforced composites for construction applications [J].
Christian, S. J. ;
Billington, S. L. .
COMPOSITES PART B-ENGINEERING, 2011, 42 (07) :1920-1928
[9]  
Christian SJ, 2009, 168 STAND U BLUM EAR
[10]  
Crank J., 1975, The Mathematics of Diffusion, V2nd