Aqueous RAFT/MADIX polymerisation of vinylphosphonic acid

被引：47

作者：

Blidi, Issam ^{[1
]}

Geagea, Roland ^{[1
]}

Coutelier, Olivier ^{[1
]}

Mazieres, Stephane ^{[1
]}

Violleau, Frederic ^{[2
]}

Destarac, Mathias ^{[1
]}

机构：

[1] Univ Toulouse 3, Lab Heterochim Fondamentale & Appl, UMR CNRS 5069, F-31062 Toulouse 9, France

[2] Univ Toulouse, Ecole Ingn Purpan, UPSP DGER 115, F-31076 Toulouse 03, France

来源：

POLYMER CHEMISTRY | 2012年 / 3卷 / 03期

关键词：

POLY(VINYL PHOSPHONIC ACID); RADICAL POLYMERIZATION; COPOLYMERS;

D O I：

10.1039/c2py00541g

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

RAFT/MADIX polymerisation of vinylphosphonic acid (VPA) was controlled in water with an O-ethyl xanthate transfer agent. This represents the first example of reversible deactivation radical polymerisation of a monomer bearing an unprotected phosphonic acid function. Hence, macromolecular engineering of polyphosphonates can now be envisioned by directly polymerising VPA in water.

引用

页码：609 / 612

页数：4

共 22 条

[1] Synthesis, microstructure, and acidity of poly (vinylphosphonic acid) [J].

Bingol, Bahar ;

Meyer, Wolfgang H. ;

Wagner, Manfred ;

Wegner, Gerhard .

MACROMOLECULAR RAPID COMMUNICATIONS, 2006, 27 (20) :1719-1724

[2] Free-radical polymerization of dimethyl vinylbenzylphosphonate controlled by tempo [J].

Boutevin, B ;

Hervaud, Y ;

Boulahna, A ;

El Asri, M .

MACROMOLECULES, 2002, 35 (17) :6511-6516

[3] INCORPORATION OF CROSS-LINKING AGENTS INTO POLY(VINYL PHOSPHONIC ACID) AS A ROUTE TO GLASS POLYALKENOATE CEMENTS OF IMPROVED COMPRESSIVE STRENGTH [J].

BRAYBROOK, JH ;

NICHOLSON, JW .

JOURNAL OF MATERIALS CHEMISTRY, 1993, 3 (04) :361-365

[4] Synthesis of block copolymers modified with phosphonate ester groups using nitroxide-mediated radical polymerizationa [J].

Britze, Antje ;

Moosmann, Katrin ;

Jaehne, Evelin ;

Adler, Hans-Juergen ;

Kuckling, Dirk .

MACROMOLECULAR RAPID COMMUNICATIONS, 2006, 27 (22) :1906-1912

[5] A process for polymerizing vinyl phosphonic acid with C6F13I perfluoroalkyl iodide chain-transfer agent [J].

David, Ghislain ;

Boyer, Cyrille ;

Tayouo, Russell ;

Seabrook, Shane ;

Ameduri, Bruno ;

Boutevin, Bernard ;

Woodward, Gary ;

Destarac, Mathias .

MACROMOLECULAR CHEMISTRY AND PHYSICS, 2008, 209 (01) :75-83

[6] Radical telomerisation of vinyl phosphonic acid with a series of chain transfer agents [J].

David, Ghislain ;

Boutevin, Bernard ;

Seabrook, Shane ;

Destarac, Mathias ;

Woodward, Gary ;

Otter, Graham .

MACROMOLECULAR CHEMISTRY AND PHYSICS, 2007, 208 (06) :635-642

[7]

Eom GT, 1998, J APPL POLYM SCI, V70, P1947, DOI 10.1002/(SICI)1097-4628(19981205)70:10<1947::AID-APP9>3.3.CO

[8]

2-9

[9] Terminology for reversible-deactivation radical polymerization previously called "controlled" radical or "living" radical polymerization (IUPAC Recommendations 2010) [J].

Jenkins, Aubrey D. ;

Jones, Richard G. ;

Moad, Graeme .

PURE AND APPLIED CHEMISTRY, 2010, 82 (02) :483-491

[10]

Kimura T., 2001, US Pat., Patent No. 6218075

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