Linking centered manganese triangles into larger clusters:: A {Mn32} truncated cube

被引：99
作者：
Scott, RTW
Parsons, S
Murugesu, M
Wernsdorfer, W
Christou, G
Brechin, EK
机构：
[1] Univ Edinburgh, Sch Chem, Edinburgh EH9 3JJ, Midlothian, Scotland
[2] Univ Florida, Dept Chem, Gainesville, FL 32611 USA
[3] CNRS, Lab Louis Neel, F-38042 Grenoble, France
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 40期
关键词：
cluster compounds; magnetic properties; manganese; O ligands; tripodal ligands;
D O I：
10.1002/anie.200501881
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Cutting Corners: Elaborate triangular arrays of Mn ions are stabilized by the tripodal ligand 1,1,1-tris(hydroxymethyl)-ethane. The self-assembled {Mn32} truncated cube (see picture) is further stabilized by end-on-bridging azide ligands and acetate groups. Such stabilization could prove to be useful in the preparation of single-molecule magnets. (Chemical Equation Presented). © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.
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收藏
页码：6540 / 6543
页数：4
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