Anionic coordination copolymerization of propylene oxide, carbon dioxide, and L-lactide

被引：8

作者：

Nysenko, Z. N. ^{[1
]}

Galiev, E. E. Said ^{[2
]}

Ilyin, M. M. ^{[2
]}

Rusak, V. V. ^{[1
]}

Glazkov, A. A. ^{[1
]}

Sakharov, A. M. ^{[1
]}

机构：

[1] Russian Acad Sci, ND Zelinsky Inst Organ Chem, Moscow 119991, Russia

[2] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, 28 Vavilova Str, Moscow 119991, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 2015年 / 64卷 / 12期

基金：

俄罗斯科学基金会;

关键词：

carbon dioxide; propylene oxide; L-lactide; terpolymerization; RING-OPENING POLYMERIZATION; ALTERNATING COPOLYMERIZATION; CATALYTIC-ACTIVITY; CO2; EPOXIDES; ZINC; PHENOXIDES; COMPLEXES; FIXATION; SYSTEMS;

D O I：

10.1007/s11172-015-1247-1

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Terpolymers with various l-lactic acid content in the polypropylene carbonate chain were synthesized by copolymerization of carbon dioxide, propylene oxide, and l-lactide. Zinc adipate was used as a catalyst. Terpolymerization products were characterized by H-1 and C-13 NMR, 2D {(1)De-D-13} HMBC, IR spectroscopy, and gel-permeation chromatography. The influence of monomer molar ratio, temperature, and reaction duration on the composition and molecular-mass characteristics of terpolymers was studied. A few questions of terpolymerization mechanism were discussed.

引用

页码：2914 / 2918

页数：5

共 50 条

[41] Microstructure and Mechanism Study of Polylactide Obtained by the Copolymerization of L-Lactide and D,L-Lactide
Zhao, Peng
Wang, Qin-Feng
Zhong, Qian
Zhang, Nai-Wen
Ren, Jie
JOURNAL OF APPLIED POLYMER SCIENCE, 2010, 115 (05) : 2955 - 2961
[42] EFFECTS OF REACTION TIME AND PRESSURE ON THE COPOLYMERIZATION OF CARBON DIOXIDE AND PROPYLENE OXIDE USING SUPPORTED ZINC GLUTARATE CATALYST
He Hu
Song Pengfei
Wu Jingshu
Xiao Min
Wang Shuanjin
Meng Yuezhong
ACTA POLYMERICA SINICA, 2010, (09) : 1148 - 1151
[43] Synthesis of Polycarbonates by Copolymerization of Carbon Dioxide and Cyclohexene Oxide Using Schiff Base Complex as Catalyst
Fan, Lidan
Qin, Gang
Cao, Shaokui
ARABIAN JOURNAL FOR SCIENCE AND ENGINEERING, 2015, 40 (10) : 2861 - 2866
[44] Highly Active Dizinc Catalyst for the Copolymerization of Carbon Dioxide and Cyclohexene Oxide at One Atmosphere Pressure
Kember, Michael R.
Knight, Paul D.
Reung, Palarp T. R.
Williams, Charlotte K.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (05) : 931 - 933
[45] Dispersion polymerization of L-lactide/ε-caprolactone in supercritical carbon dioxide
Shiping Zhan
Qingchun Qi
Weijing Wang
Shuhua Chen
Jingchang Wang
Mingming Li
Shiqiang Ding
Journal of Polymer Research, 2015, 22
[46] Copolymerization of L-Lactide and ε-Caprolactone in Supercritical Fluid
Prabowo, Benedictus
Choi, Dong Hoon
Kim, Soo Hyun
MACROMOLECULAR RESEARCH, 2009, 17 (08) : 575 - 579
[47] Stereocomplex of Poly(propylene carbonate): Synthesis of Stereogradient Poly(propylene carbonate) by Regio- and Enantioselective Copolymerization of Propylene Oxide with Carbon Dioxide
Nakano, Koji
Hashimoto, Shinichi
Nakamura, Mitsuru
Kamada, Toshihiro
Nozaki, Kyoko
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (21) : 4868 - 4871
[48] Semi-Batch Copolymerization of Propylene Oxide and Carbon Dioxide
Noernberg, Benjamin
Spottog, Carmen
Rahlf, Anne
Korashvili, Revaz
Berlin, Claas
Luinstra, Gerrit A.
MACROMOLECULAR SYMPOSIA, 2013, 333 (01) : 190 - 196
[49] Terpolymerization of propylene oxide, carbon dioxide, and trimethylene carbonate
Nysenko, Z. N.
Said-Galiev, E. E.
Nikiforova, G. G.
Buzin, M., I
Glazkov, A. A.
Il'in, M. M.
Belyaev, G. A.
Rusak, V. V.
Sakharov, A. M.
RUSSIAN CHEMICAL BULLETIN, 2022, 71 (08) : 1770 - 1776
[50] Copolymerization and terpolymerization of carbon dioxide/propylene oxide/phthalic anhydride using a (salen)Co(III) complex tethering four quaternary ammonium salts
Jeon, Jong Yeob
Eo, Seong Chan
Varghese, Jobi Kodiyan
Lee, Bun Yeoul
BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY, 2014, 10 : 1787 - 1795

← 1 2 3 4 5 →