Carboxylation of naphthols with sodium ethyl carbonate

被引:0
作者
Suerbaev, KA
Mikhnenko, OE
Akhmetova, GB
Shalmagambetov, KM
Chepaikin, EG
机构
[1] Al Farabi Kazakh Natl Univ, Alma Ata 480012, Kazakhstan
[2] Russian Acad Sci, Inst Struct Macrokinet & Mat Sci, Moscow 142432, Russia
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中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The carboxylation of alpha- and beta-naphthols with sodium ethyl carbonate was studied. Conditions for the regioselective carboxylation of alpha-naphthol in the 2- and 4-positions and beta-naphthol in the 3-position were found. Simple and convenient methods for the preparation of 1-hydroxy-2-naphthoic, 1-hydroxy-4-naphthoic, and 2-hydroxy-3-naphthoic acids were developed.
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页码:335 / 337
页数:3
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