Oxidation of organic sulfides and disulfides with a tert-butyl hydroperoxide-aluminum tri-tert-butoxide system

被引：4
作者：
Zaburdaeva, E. A. [1 ]
Dodonov, V. A. [1 ]
机构：
[1] NI Lobachevsky Nizhny Novgorod State Univ, Nizhnii Novgorod 603950, Russia
来源：
RUSSIAN CHEMICAL BULLETIN | 2011年 / 60卷 / 01期
基金：
俄罗斯基础研究基金会;
关键词：
oxidation; aluminum tri-tert-butoxide; tert-butyl hydroperoxide; activated dioxygen; alkynyl sulfides; sulfones; diphenyl disulfide; S-phenyl benzenethiosulfonate; LIQUID-PHASE OXIDATION;
D O I：
10.1007/s11172-011-0029-7
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Methyl phenylethynyl and phenyl phenylethynyl sulfides are selectively converted into methyl phenylethynyl and phenyl phenylethynyl sulfones, respectively, under the action of system tert-butyl hydroperoxide-aluminum tri-tert-butoxide in benzene at 20 degrees C. The analogous oxidation of diphenyl disulfide results in S-phenyl benzenethiosulfonate.
引用
收藏
页码：185 / 187
页数：3
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