Oxidation of dimethoxymethane in a jet-stirred reactor

被引：80
作者：
Daly, CA
Simmie, JM [1 ]
Dagaut, P
Cathonnet, M
机构：
[1] Natl Univ Ireland Univ Coll Galway, Dept Chem, Galway, Ireland
[2] CNRS, LCSR, F-45071 Orleans, France
来源：
COMBUSTION AND FLAME | 2001年 / 125卷 / 03期
关键词：
D O I：
10.1016/S0010-2180(01)00227-9
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
The oxidation of dimethoxymethane has been investigated in a jet-stirred reactor at pressures of 5.07 bar, temperatures of 800 to 1200 K, and equivalence ratios of 0.444, 0.889. and 1.778. Concentration profiles of carbon monoxide. carbon dioxide, hydrogen, methane, formaldehyde, methanol, acetaldehyde, methyl formate, ethane, ethene. ethyne. propane, and propene were obtained by probe sampling and gas chromatography analysis. A detailed chemical kinetic model accounts quite well for the bulk of the measurements; at the lower end of the temperature scale it is necessary to postulate very low activation energy decompositions of dimethoxymethane. most probably surface-catalyzed reactions, one leading to formaldehyde + dimethyl ether, the other to methanol + acetaldehyde: H3COCH2OCH3 --> H2CO + H3COCH3 H3COCH2OCH3 --> CH3OH + CH3HCO (C) 2001 by The Combustion Institute.
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页码：1106 / 1117
页数：12
相关论文
共 47 条
[1]  
[Anonymous], 971677 SAE
[2]   EVALUATED KINETIC DATA FOR COMBUSTION MODELING [J].
BAULCH, DL ;
COBOS, CJ ;
COX, RA ;
ESSER, C ;
FRANK, P ;
JUST, T ;
KERR, JA ;
PILLING, MJ ;
TROE, J ;
WALKER, RW ;
WARNATZ, J .
JOURNAL OF PHYSICAL AND CHEMICAL REFERENCE DATA, 1992, 21 (03) :411-734
[3]  
Brocard J.C., 1980, OXID COMMUN, V1, P321
[4]   INVESTIGATION OF THE REACTIONS OF DIETHYLETHER, NORMAL-DIPROPYLETHER AND NORMAL-DIBUTYLETHER WITH O(3P) IN THE GAS-PHASE [J].
BUCHTA, C ;
FRERICHS, H ;
STUCKEN, D ;
TAPPE, M ;
WAGNER, HG .
ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-INTERNATIONAL JOURNAL OF RESEARCH IN PHYSICAL CHEMISTRY & CHEMICAL PHYSICS, 1991, 174 :129-137
[5]   Low-temperature oxidation of MTBE in a high-pressure jet-stirred flow reactor [J].
Ciajolo, A ;
DAnna, A ;
Kurz, M .
COMBUSTION SCIENCE AND TECHNOLOGY, 1997, 123 (1-6) :49-61
[6]   ARE REACTION-RATE COEFFICIENTS ADDITIVE - REVISED TRANSITION-STATE THEORY CALCULATIONS FOR OH + ALKANE REACTIONS [J].
COHEN, N .
INTERNATIONAL JOURNAL OF CHEMICAL KINETICS, 1991, 23 (05) :397-417
[7]  
Curran HJ, 1998, INT J CHEM KINET, V30, P229, DOI 10.1002/(SICI)1097-4601(1998)30:3<229::AID-KIN9>3.0.CO
[8]  
2-U
[9]  
Dagaut P, 1996, TWENTY-SIXTH SYMPOSIUM (INTERNATIONAL) ON COMBUSTION, VOLS 1 AND 2, P627
[10]   KINETIC MODELING OF ETHYLENE OXIDATION [J].
DAGAUT, P ;
CATHONNET, M ;
BOETTNER, JC ;
GAILLARD, F .
COMBUSTION AND FLAME, 1988, 71 (03) :295-312
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