Superparamagnetic nanoparticle-supported catalysis of Suzuki cross-coupling reactions

被引：363
作者：
Stevens, PD
Fan, JD
Gardimalla, HMR
Yen, M
Gao, Y
机构：
[1] So Illinois Univ, Dept Chem & Biochem, Carbondale, IL 62901 USA
[2] So Illinois Univ, Mat Technol Ctr, Carbondale, IL 62901 USA
来源：
ORGANIC LETTERS | 2005年 / 7卷 / 11期
关键词：
D O I：
10.1021/ol050218w
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Emulsion polymerization was examined as a novel route for the synthesis of core/shell superparamagnetic nanoparticles consisting of a highly crystalline gamma-Fe2O3 core and a very thin polymeric shell wall. These nanoparticles were used as soluble supports for immobilizing Pd catalysts to promote Suzuki cross-coupling reactions. Recovery of catalysts was facilely achieved by applying a permanent magnet externally. Isolated catalysts were reused for new rounds of reactions without significant loss of their catalytic activity.
引用
收藏
页码：2085 / 2088
页数：4
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