Structural, optical and magnetic properties of CdZnS and Ni:CdZnS nanoparticles

被引：7

作者：

Horoz, Sabit ^{[1
]}

Akyol, Mustafa ^{[2
]}

Ekicibil, Ahmet ^{[2
]}

Sahin, Omer ^{[3
]}

机构：

[1] Siirt Univ, Fac Art & Sci, Dept Phys, TR-56100 Siirt, Turkey

[2] Cukurova Univ, Fac Art & Sci, Dept Phys, TR-01330 Adana, Turkey

[3] Siirt Univ, Dept Chem Engn, Fac Engn & Architecture, TR-56100 Siirt, Turkey

来源：

JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS | 2017年 / 28卷 / 23期

关键词：

ROOM-TEMPERATURE FERROMAGNETISM; QUANTUM DOTS; THIN-FILMS; ZNS; NANOCRYSTALS; LUMINESCENCE; PHOTOLUMINESCENCE; GROWTH; NANOWIRES; EMISSION;

D O I：

10.1007/s10854-017-7765-x

中图分类号：

TM [电工技术]; TN [电子技术、通信技术];

学科分类号：

0808 ; 0809 ;

摘要：

In this study, Cadmium Zinc Sulfide (CdZnS) and Ni-alloyed CdZnS (Ni:CdZnS) nanoparticles (NPs) prepared at room temperature by co-precipitation method using mercaptoethanol as a capping agent for the first time. The structural, optical and magnetic properties of NPs were characterized by using X-ray diffraction (XRD), ultraviolet-visible (UV-Vis) spectroscopy and physical property measurement system (PPMS). The average crystalline size of cubic phase of Ni:CdZnS NPs estimated from the XRD and optical absorption measurements was found smaller than that of cubic phase of CdZnS NPs. The optical measurements showed that the absorption edge of Ni:CdZnS NPs slightly shifts towards the lower wavelengths compare to un-doped CdZnS NPs. The band gap of CdZnS NPs (3.79 eV) increases with Ni dopant (4.02 eV) into the CdZnS structure. The temperature (M (T)) and field (M (H)) dependence magnetization data collected from PPMS indicated that a ferromagnetic behavior is observed in Ni:CdZnS NPs whereas CdZnS NPs show diamagnetic behavior.

引用

页码：18193 / 18199

页数：7

共 55 条

[41] Luminescence decay kinetics of Mn2+-doped ZnS nanoclusters grown in reverse micelles [J].

Smith, BA ;

Zhang, JZ ;

Joly, A ;

Liu, J .

PHYSICAL REVIEW B, 2000, 62 (03) :2021-2028

[42] Preparation of nanosized crystalline CdS particles by the hydrothermal treatment [J].

So, WW ;

Jang, JS ;

Rhee, YW ;

Kim, KJ ;

Moon, SJ .

JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2001, 237 (01) :136-141

[43]

Sobhani-Nasab A., 2016, J MATER SCI-MATER EL, V27, P11951

[44]

Sobhani-Nasab A., 2017, J MOL STRUCT, V1139, P435

[45] Structural and optical characterization of Ni-doped CdS quantum dots [J].

Thambidurai, M. ;

Muthukumarasamy, N. ;

Agilan, S. ;

Arul, N. Sabari ;

Murugan, N. ;

Balasundaraprabhu, R. .

JOURNAL OF MATERIALS SCIENCE, 2011, 46 (09) :3200-3206

[46] Tunable Dual Emission in Doped Semiconductor Nanocrystals [J].

Vlaskin, Vladimir A. ;

Janssen, Nils ;

van Rijssel, Jos ;

Beaulac, Remi ;

Gamelin, Daniel R. .

NANO LETTERS, 2010, 10 (09) :3670-3674

[47]

Walter T., 1992, PROC 11 EC PHOTOVOLT, P124

[48] MOLECULAR-BEAM EPITAXIAL-GROWTH OF CDZNS USING ELEMENTAL SOURCES [J].

WU, BJ ;

CHENG, H ;

GUHA, S ;

HAASE, MA ;

DEPUYDT, JM ;

MEISHAUGEN, G ;

QIU, J .

APPLIED PHYSICS LETTERS, 1993, 63 (21) :2935-2937

[49] Luminescence characteristics of impurities-activated ZnS nanocrystals prepared in microemulsion with hydrothermal treatment [J].

Xu, SJ ;

Chua, SJ ;

Liu, B ;

Gan, LM ;

Chew, CH ;

Xu, GQ .

APPLIED PHYSICS LETTERS, 1998, 73 (04) :478-480

[50] OPTICAL-TRANSITIONS IN RF-SPUTTERED CUINXGA1-XSE2 THIN-FILMS [J].

YAMAGUCHI, T ;

MATSUFUSA, J ;

YOSHIDA, A .

JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS, 1992, 31 (6A) :L703-L705

← 1 2 3 4 5 6 →