Curious cases of 3,6-dinitropyrazolo[4,3-c]pyrazole-based energetic cocrystals with high nitrogen content: an alternative to salt formation

被引:49
作者
Zhang, Jiaheng [1 ]
Parrish, Damon A. [2 ]
Shreeve, Jean'ne M. [1 ]
机构
[1] Univ Idaho, Dept Chem, Moscow, ID 83844 USA
[2] Naval Res Lab, Washington, DC 20375 USA
基金
美国国家科学基金会;
关键词
CO-CRYSTALS; PI-STACKING; PERFORMANCE; STABILITY; DESIGN; CL-20;
D O I
10.1039/c5cc01745a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Two structurally interesting 3,6-dinitropyrazolo[4,3-c] pyrazole-based energetic cocrystals were prepared and confirmed by single crystal X-ray diffraction. As novel energetic materials, these two unusual neutral acid-base complexes possess high nitrogen content, good detonation properties, and improved impact and friction sensitivities which highlight their potential energetic applications.
引用
收藏
页码:7337 / 7340
页数:4
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