A molecular metal ferromagnet from the organic donor bis(ethylenedithio)tetraselenafulvalene and bimetallic oxalate complexes

被引：180

作者：

Alberola, A ^{[1
]}

Coronado, E ^{[1
]}

Galán-Mascarós, JR ^{[1
]}

Giménez-Saiz, C ^{[1
]}

Gómez-García, CJ ^{[1
]}

机构：

[1] Univ Valencia, Inst Ciencia Mol, E-46100 Burjassot, Spain

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2003年 / 125卷 / 36期

关键词：

CHARGE-TRANSFER SALTS; II = MN; MAGNETS; FE; ANIONS; BETS; TTF; ZN; CO;

D O I：

10.1021/ja035772k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new dual-function hybrid molecular material has been obtained from the organic donor bis(ethylenedithio)tetraselenafulvalene and the honeycomb oxalate-based bimetallic network [MnCr(ox)3]-. This multilayer material consists of layers of the inorganic anionic 2D network, responsible for the appearance of ferromagnetic ordering below 5.3 K, alternating with segregated layers of the organic cation radical responsible for the transport properties: metal-like conductivity is observed from room temperature down to 150 K. Copyright © 2003 American Chemical Society.

引用

页码：10774 / 10775

页数：2

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