DISSOLUTION OF CELLULOSE IN 1-BUTYL-3-METHYLIMIDAZOLIUM CHLORIDE IONIC LIQUID ASSISTED WITH ULTRASONIC IRRADIATION

被引:0
作者
Lan Wu [1 ]
Liu Chuanfu [1 ]
Yue Fengxia
Sun Runcang [1 ]
机构
[1] S China Univ Technol, State Key Lab Pulp & Paper Engn, Guangzhou 510640, Guangdong, Peoples R China
来源
RESEARCH PROGRESS IN PAPER INDUSTRY AND BIOREFINERY (4TH ISETPP), VOLS 1-3 | 2010年
关键词
cellulose; ionic liquid; ultrasonic; dissolution;
D O I
暂无
中图分类号
Q81 [生物工程学(生物技术)]; Q93 [微生物学];
学科分类号
071005 ; 0836 ; 090102 ; 100705 ;
摘要
The dissolution of cellulose was investigated in ionic liquid [C(4)mim]Cl assisted with ultrasound irradiation. The effects of ultrasound power and irradiation duration on cellulose dissolution and the regenerated cellulose properties were discussed. The physicochemical properties of the regenerated cellulosic preparations were also characterized by FT-IR, solid-state CP/MAS (13)C NMR, wide angle X-ray diffraction and thermal analysis. It was found that the chemical structure of regenerated cellulose did not change obviously under the conditions used. It was suggested that the crystalline structure of cellulose was converted from cellulose I to the mixture of amorphous cellulose and cellulose II after dissolution and regeneration.
引用
收藏
页码:177 / 180
页数:4
相关论文
共 8 条
[1]   Cellulose dissolution with polar ionic liquids under mild conditions: required factors for anions [J].
Fukaya, Yukinobu ;
Hayashi, Kensaku ;
Wada, Masahisa ;
Ohno, Hiroyuki .
GREEN CHEMISTRY, 2008, 10 (01) :44-46
[2]   New developments in dissolving and processing of cellulose in ionic liquids [J].
Hermanutz, Frank ;
Gaehr, Frank ;
Uerdingen, Eric ;
Meister, Frank ;
Kosan, Birgit .
MACROMOLECULAR SYMPOSIA, 2008, 262 :23-27
[3]   Sonochemistry of carbohydrate compounds [J].
Kardos, N ;
Luche, JL .
CARBOHYDRATE RESEARCH, 2001, 332 (02) :115-131
[4]   Dissolution and forming of cellulose with ionic liquids [J].
Kosan, Birgit ;
Michels, Christoph ;
Meister, Frank .
CELLULOSE, 2008, 15 (01) :59-66
[5]   Crystalline structure analysis of cellulose treated with sodium hydroxide and carbon dioxide by means of X-ray diffraction and FTIR spectroscopy [J].
Oh, SY ;
Yoo, DI ;
Shin, Y ;
Kim, HC ;
Kim, HY ;
Chung, YS ;
Park, WH ;
Youk, JH .
CARBOHYDRATE RESEARCH, 2005, 340 (15) :2376-2391
[6]   Influence of ultrasound treatment on accessibility and regioselective oxidation reactivity of cellulose [J].
Tang, AM ;
Zhang, HW ;
Chen, G ;
Xie, GH ;
Liang, WZ .
ULTRASONICS SONOCHEMISTRY, 2005, 12 (06) :467-472
[7]   Ionic liquid salt-induced inactivation and unfolding of cellulase from Trichoderma reesei [J].
Turner, MB ;
Spear, SK ;
Huddleston, JG ;
Holbrey, JD ;
Rogers, RD .
GREEN CHEMISTRY, 2003, 5 (04) :443-447
[8]   1-Allyl-3-methylimidazolium chloride room temperature ionic liquid: A new and powerful nonderivatizing solvent for cellulose [J].
Zhang, H ;
Wu, J ;
Zhang, J ;
He, JS .
MACROMOLECULES, 2005, 38 (20) :8272-8277