Metal Acetylacetonates as a Source of Metals for Aqueous Synthesis of Metal-Organic Frameworks

被引：43

作者：

Avci-Camur, Ceren ^{[1
]}

Perez-Carvajal, Javier ^{[1
]}

Imaz, Inhar ^{[1
]}

Maspoch, Daniel ^{[1
,2
]}

机构：

[1] CSIC, ICN2, Barcelona 08193, Spain

[2] ICREA, Pg Lluis Co 23, Barcelona 08010, Spain

来源：

ACS SUSTAINABLE CHEMISTRY & ENGINEERING | 2018年 / 6卷 / 11期

基金：

欧盟地平线“2020”; 欧盟第七框架计划;

关键词：

Metal-organic frameworks; Green synthesis; Water; TEMPERATURE SYNTHESIS; WATER-ADSORPTION; MOFS; UIO-66; POLYMERIZATION;

D O I：

10.1021/acssuschemeng.8b03180

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Demand continues for environmentally sound, high-yielding processes for the large-scale production of metal-organic frameworks (MOFs). Here we describe the use of metal acetylacetonate complexes as an alternative source of metals for the aqueous synthesis of MOFs. We have synthesized several carboxylate-based Zr(IV)-(UiO-66-NH2, Zr-fumarate, UiO-66-(OH)(2), UiO-66-COOH and UiO-66-(COOH)(2)), Fe(III)-(MIL-88A) and Al(III)-(CAU-10) porous MOFs from their corresponding metal acetylacetonates in good yields (typically >85%) and, in some cases, at room temperature.

引用

页码：14554 / 14560

页数：13

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[51] Temperature-Triggered Collection and Release of Water from Fogs by a Sponge-Like Cotton Fabric [J].