Metal Acetylacetonates as a Source of Metals for Aqueous Synthesis of Metal-Organic Frameworks

被引：43

作者：

Avci-Camur, Ceren ^{[1
]}

Perez-Carvajal, Javier ^{[1
]}

Imaz, Inhar ^{[1
]}

Maspoch, Daniel ^{[1
,2
]}

机构：

[1] CSIC, ICN2, Barcelona 08193, Spain

[2] ICREA, Pg Lluis Co 23, Barcelona 08010, Spain

来源：

ACS SUSTAINABLE CHEMISTRY & ENGINEERING | 2018年 / 6卷 / 11期

基金：

欧盟地平线“2020”; 欧盟第七框架计划;

关键词：

Metal-organic frameworks; Green synthesis; Water; TEMPERATURE SYNTHESIS; WATER-ADSORPTION; MOFS; UIO-66; POLYMERIZATION;

D O I：

10.1021/acssuschemeng.8b03180

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Demand continues for environmentally sound, high-yielding processes for the large-scale production of metal-organic frameworks (MOFs). Here we describe the use of metal acetylacetonate complexes as an alternative source of metals for the aqueous synthesis of MOFs. We have synthesized several carboxylate-based Zr(IV)-(UiO-66-NH2, Zr-fumarate, UiO-66-(OH)(2), UiO-66-COOH and UiO-66-(COOH)(2)), Fe(III)-(MIL-88A) and Al(III)-(CAU-10) porous MOFs from their corresponding metal acetylacetonates in good yields (typically >85%) and, in some cases, at room temperature.

引用

收藏

页码：14554 / 14560

页数：13

相关论文

共 52 条

[21] A Modulated Hydrothermal (MHT) Approach for the Facile Synthesis of UiO66-Type MOFs [J].

Hu, Zhigang ;

Peng, Yongwu ;

Kang, Zixi ;

Qian, Yuhong ;

Zhao, Dan .

INORGANIC CHEMISTRY, 2015, 54 (10) :4862-4868

[22]

Hudson R. L, 1993, US Patent, Patent No. [US5 393 831, 5393831]

[23] Nitroxide polymer networks formed by Michael addition: on site-cured electrode-active organic coating [J].

Ibe, Takeshi ;

Frings, Rainer B. ;

Lachowicz, Artur ;

Kyo, Soichi ;

Nishide, Hiroyuki .

CHEMICAL COMMUNICATIONS, 2010, 46 (20) :3475-3477

[24] Programming MOFs for water sorption: amino-functionalized MIL-125 and UiO-66 for heat transformation and heat storage applications [J].

Jeremias, Felix ;

Lozan, Vasile ;

Henninger, Stefan K. ;

Janiak, Christoph .

DALTON TRANSACTIONS, 2013, 42 (45) :15967-15973

[25] Metal-organic frameworks meet scalable and sustainable synthesis [J].

Julien, Patrick A. ;

Mottillo, Cristina ;

Friscic, Tomislav .

GREEN CHEMISTRY, 2017, 19 (12) :2729-2747

[26] Metal-Organic Frameworks for Water Harvesting from Air [J].

Kalmutzki, Markus J. ;

Diercks, Christian S. ;

Yaghi, Omar M. .

ADVANCED MATERIALS, 2018, 30 (37)

[27] Water harvesting from air with metal-organic frameworks powered by natural sunlight [J].

Kim, Hyunho ;

Yang, Sungwoo ;

Rao, Sameer R. ;

Narayanan, Shankar ;

Kapustin, Eugene A. ;

Furukawa, Hiroyasu ;

Umans, Ari S. ;

Yaghi, Omar M. ;

Wang, Evelyn N. .

SCIENCE, 2017, 356 (6336) :430-432

[28] Scalable Green Synthesis and Full-Scale Test of the Metal-Organic Framework CAU-10-H for Use in Adsorption-Driven Chillers [J].

Lenzen, Dirk ;

Bendix, Phillip ;

Reinsch, Helge ;

Froehlich, Dominik ;

Kummer, Harry ;

Moellers, Marc ;

Huegenell, Philipp P. C. ;

Glaeser, Roger ;

Henninger, Stefan ;

Stock, Norbert .

ADVANCED MATERIALS, 2018, 30 (06)

[29]

Levis R.J., 1992, Sax's Dangerous Properties of Industrial Materials, V8th

[30] Highly Water-Stable Zirconium Metal Organic Framework UiO-66 Membranes Supported on Alumina Hollow Fibers for Desalination [J].

Liu, Xinlei ;

Demir, Nilay Keser ;

Wu, Zhentao ;

Li, Kang .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2015, 137 (22) :6999-7002

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