Metal Acetylacetonates as a Source of Metals for Aqueous Synthesis of Metal-Organic Frameworks

被引：43
作者：
Avci-Camur, Ceren [1 ]
Perez-Carvajal, Javier [1 ]
Imaz, Inhar [1 ]
Maspoch, Daniel [1 ,2 ]
机构：
[1] CSIC, ICN2, Barcelona 08193, Spain
[2] ICREA, Pg Lluis Co 23, Barcelona 08010, Spain
来源：
ACS SUSTAINABLE CHEMISTRY & ENGINEERING | 2018年 / 6卷 / 11期
基金：
欧盟地平线“2020”; 欧盟第七框架计划;
关键词：
Metal-organic frameworks; Green synthesis; Water; TEMPERATURE SYNTHESIS; WATER-ADSORPTION; MOFS; UIO-66; POLYMERIZATION;
D O I：
10.1021/acssuschemeng.8b03180
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Demand continues for environmentally sound, high-yielding processes for the large-scale production of metal-organic frameworks (MOFs). Here we describe the use of metal acetylacetonate complexes as an alternative source of metals for the aqueous synthesis of MOFs. We have synthesized several carboxylate-based Zr(IV)-(UiO-66-NH2, Zr-fumarate, UiO-66-(OH)(2), UiO-66-COOH and UiO-66-(COOH)(2)), Fe(III)-(MIL-88A) and Al(III)-(CAU-10) porous MOFs from their corresponding metal acetylacetonates in good yields (typically >85%) and, in some cases, at room temperature.
引用
收藏
页码：14554 / 14560
页数：13
相关论文
共 52 条
[1]  
[Anonymous], 2013, CN Patent, Patent No. [CN103 086 857, 103086857]
[2]   Aqueous production of spherical Zr-MOF beads via continuous-flow spray-drying [J].
Avci-Camur, Ceren ;
Troyano, Javier ;
Perez-Carvajal, Javier ;
Legrand, Alexandre ;
Farrusseng, David ;
Imaz, Inhar ;
Maspoch, Daniel .
GREEN CHEMISTRY, 2018, 20 (04) :873-878
[3]   Zr-based metal-organic frameworks: design, synthesis, structure, and applications [J].
Bai, Yan ;
Dou, Yibo ;
Xie, Lin-Hua ;
Rutledge, William ;
Li, Jian-Rong ;
Zhou, Hong-Cai .
CHEMICAL SOCIETY REVIEWS, 2016, 45 (08) :2327-2367
[4]   Enhanced selectivity of CO2 over CH4 in sulphonate-, carboxylate- and iodo-functionalized UiO-66 frameworks [J].
Biswas, Shyam ;
Zhang, Jian ;
Li, Zhibao ;
Liu, Ying-Ya ;
Grzywa, Maciej ;
Sun, Lixian ;
Volkmer, Dirk ;
Van der Voort, Pascal .
DALTON TRANSACTIONS, 2013, 42 (13) :4730-4737
[5]   Structure-property relationships of water adsorption in metal-organic frameworks [J].
Canivet, Jerome ;
Bonnefoy, Jonathan ;
Daniel, Cecile ;
Legrand, Alexandre ;
Coasne, Benoit ;
Farrusseng, David .
NEW JOURNAL OF CHEMISTRY, 2014, 38 (07) :3102-3111
[6]   A new zirconium inorganic building brick forming metal organic frameworks with exceptional stability [J].
Cavka, Jasmina Hafizovic ;
Jakobsen, Soren ;
Olsbye, Unni ;
Guillou, Nathalie ;
Lamberti, Carlo ;
Bordiga, Silvia ;
Lillerud, Karl Petter .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (42) :13850-13851
[7]   The crosslinking reaction of acrylic PSA using chelate metal acetylacetonates [J].
Czech, Zbigniew ;
Wojciechowicz, Marta .
EUROPEAN POLYMER JOURNAL, 2006, 42 (09) :2153-2160
[8]   Manufacture of dense CAU-10-H coatings for application in adsorption driven heat pumps: optimization and characterization [J].
de Lange, M. F. ;
Zeng, T. ;
Vlugt, T. J. H. ;
Gascon, J. ;
Kapteijn, F. .
CRYSTENGCOMM, 2015, 17 (31) :5911-5920
[9]   Room-Temperature Synthesis of UiO-66 and Thermal Modulation of Densities of Defect Sites [J].
DeStefano, Matthew R. ;
Islamoglu, Timur ;
Hupp, Joseph T. ;
Farha, Omar K. .
CHEMISTRY OF MATERIALS, 2017, 29 (03) :1357-1361
[10]   Controlled Formation of Hierarchical Metal-Organic Frameworks Using CO2-Expanded Solvent Systems [J].
Doan, Huan V. ;
Fang, Yanan ;
Yao, Bingqing ;
Dong, Zhili ;
White, Timothy J. ;
Sartbaeva, Asel ;
Hintermair, Ulrich ;
Ting, Valeska P. .
ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2017, 5 (09) :7887-7893
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