Fabrication of polymer/layered silicate intercalated nanofibrous mats and their bacterial inhibition activity

被引:68
作者
Deng, Hongbing [1 ,2 ]
Li, Xueyong [3 ]
Ding, Bin [1 ,4 ]
Du, Yumin [2 ]
Li, Guoxiang [2 ]
Yang, Jianhong [2 ]
Hu, Xianwen [2 ]
机构
[1] Donghua Univ, Coll Mat Sci & Engn, State Key Lab Modificat Chem Fibers & Polymer Mat, Shanghai 201620, Peoples R China
[2] Wuhan Univ, Sch Resource & Environm Sci, Wuhan 430079, Peoples R China
[3] Fourth Mil Med Univ, Tangdu Hosp, Dept Plast Surg, Xian 710038, Peoples R China
[4] Donghua Univ, Modern Text Inst, Nanomat Res Ctr, Shanghai 200051, Peoples R China
关键词
Electrospinning; Chitosan; Layered silicate; Poly(vinyl alcohol); Bacterial inhibition activity; POLYMER NANOCOMPOSITES; ANTIMICROBIAL ACTIVITY; CLAY NANOCOMPOSITES; CHITOSAN; GLYCOL); FIBERS; FILMS; PVA;
D O I
10.1016/j.carbpol.2010.09.008
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
A uniform electrospun nanofibrous membrane was fabricated from chitosan (CS)-polyvinyl alcohol (PVA)/organic rectonte (OREC) with different mixing ratios by solution-mixing process and eleltrospinning technologies The morphology intercalation between polymer and OREC and bacterial inhibition activity of the electrospun membranes were investigated Field emission scanning electron microscopy showed uniform fibrous structure generated with the addition of OREC Energy-dispersive X-ray spectroscopy results confirmed the existence of OREC on the surface of electrospun membranes Fourier transform infrared spectra and small angle X-ray diffraction results verified that the interlayer of OREC was intercalated by CS and PVA chains successfully The controllable interlayer distance of OREC was enlarged from 3 68 to 4 28 rim The membranes had enhanced bacterial inhibition activity with the addition of OREC (C) 2010 Elsevier Ltd All rights reserved
引用
收藏
页码:973 / 978
页数:6
相关论文
共 38 条
[1]   An investigation on the short-term biodegradability of chitosan with various molecular weights and degrees of deacetylation [J].
Bagheri-Khoulenjani, S. ;
Taghizadeh, S. M. ;
Mirzadeh, H. .
CARBOHYDRATE POLYMERS, 2009, 78 (04) :773-778
[2]   Chitosan and its salts for mucosal and transmucosal delivery [J].
Bonferoni, Maria Cristina ;
Sandri, Giuseppina ;
Rossi, Silvia ;
Ferrari, Franca ;
Caramella, Carla .
EXPERT OPINION ON DRUG DELIVERY, 2009, 6 (09) :923-939
[3]   Chitosan-clay nanocomposites: application as electrochemical sensors [J].
Darder, M ;
Colilla, M ;
Ruiz-Hitzky, E .
APPLIED CLAY SCIENCE, 2005, 28 (1-4) :199-208
[4]   Biopolymer-clay nanocomposites based on chitosan intercalated in montmorillonite [J].
Darder, M ;
Colilla, M ;
Ruiz-Hitzky, E .
CHEMISTRY OF MATERIALS, 2003, 15 (20) :3774-3780
[5]   Electrospinning of chitosan nanofibrous structures: feasibility study [J].
De Vrieze, Sander ;
Westbroek, Philippe ;
Van Camp, Tamara ;
Van Langenhove, Lieva .
JOURNAL OF MATERIALS SCIENCE, 2007, 42 (19) :8029-8034
[6]   Fabrication of blend biodegradable nanofibrous nonwoven mats via multi-jet electrospinning [J].
Ding, B ;
Kimura, E ;
Sato, T ;
Fujita, S ;
Shiratori, S .
POLYMER, 2004, 45 (06) :1895-1902
[7]   Formation of novel 2D polymer nanowebs via electrospinning [J].
Ding, Bin ;
Li, Chunrong ;
Miyauchi, Yasuhiro ;
Kuwaki, Oriha ;
Shiratori, Seimei .
NANOTECHNOLOGY, 2006, 17 (15) :3685-3691
[8]   Electrospinning of chitosan dissolved in concentrated acetic acid solution [J].
Geng, XY ;
Kwon, OH ;
Jang, JH .
BIOMATERIALS, 2005, 26 (27) :5427-5432
[9]   Electrospun three-dimensional hyaluronic acid nanofibrous scaffolds [J].
Ji, Y ;
Ghosh, K ;
Shu, XZ ;
Li, BQ ;
Sokolov, JC ;
Prestwich, GD ;
Clark, RAF ;
Rafailovich, MH .
BIOMATERIALS, 2006, 27 (20) :3782-3792
[10]  
LEE SW, 2009, J TRIBOL T ASME, V131, pNI195