A membrane-free interfacial battery with high energy density

被引:25
作者
Xu, Pengcheng [1 ]
Xie, Congxin [1 ,2 ]
Wang, Chenhui [1 ,2 ]
Lai, Qinzhi [1 ]
Wang, Wei [3 ]
Zhang, Huamin [1 ,4 ]
Li, Xianfeng [1 ,4 ]
机构
[1] Chinese Acad Sci, Div Energy Storage, Dalian Inst Chem Phys, Zhongshan Rd 457, Dalian 116023, Peoples R China
[2] Univ Chinese Acad Sci, Beijing 100039, Peoples R China
[3] Pacific Northwest Natl Lab, Energy & Environm Directorate, POB 999, Richland, WA 99352 USA
[4] Collaborat Innovat Ctr Chem Energy Mat iChEM, Dalian 116023, Peoples R China
关键词
REDOX FLOW BATTERY; CARBON NANOTUBES; PERFORMANCE; STORAGE; BROMINE; COUPLE; CATHOLYTE; PROGRESS;
D O I
10.1039/c8cc06048g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A new concept of the membrane-free interfacial battery based on a biphasic system was proposed for the first time. An aqueous ZnBr2 solution was used as a negative electrolyte, while Br-2 in CCl4 served as a positive electrolyte. This interfacial Zn/Br-2 battery demonstrated a very impressive performance with a CE of 96% and an EE of 81% at a current density of 15 mA cm(-2).
引用
收藏
页码:11626 / 11629
页数:4
相关论文
共 30 条
  • [1] Membrane-less hydrogen bromine flow battery
    Braff, William A.
    Bazant, Martin Z.
    Buie, Cullen R.
    [J]. NATURE COMMUNICATIONS, 2013, 4
  • [2] Study on a high current density redox flow battery with tin(II)/tin as negative couple
    Chen, Fuyu
    Sun, Qing
    Gao, Wei
    Liu, Jianguo
    Yan, Chuanwei
    Liu, Qingyu
    [J]. JOURNAL OF POWER SOURCES, 2015, 280 : 227 - 230
  • [3] Ionic liquid-mediated aqueous redox flow batteries for high voltage applications
    Chen, Ruiyong
    Hempelmann, Rolf
    [J]. ELECTROCHEMISTRY COMMUNICATIONS, 2016, 70 : 56 - 59
  • [4] Comparative analysis for various redox flow batteries chemistries using a cost performance model
    Crawford, Alasdair
    Viswanathan, Vilayanur
    Stephenson, David
    Wang, Wei
    Thomsen, Edwin
    Reed, David
    Li, Bin
    Balducci, Patrick
    Kintner-Meyer, Michael
    Sprenkle, Vincent
    [J]. JOURNAL OF POWER SOURCES, 2015, 293 : 388 - 399
  • [5] A review of energy storage technologies for wind power applications
    Diaz-Gonzalez, Francisco
    Sumper, Andreas
    Gomis-Bellmunt, Oriol
    Villafafila-Robles, Roberto
    [J]. RENEWABLE & SUSTAINABLE ENERGY REVIEWS, 2012, 16 (04) : 2154 - 2171
  • [6] Molecular engineering of organic electroactive materials for redox flow batteries
    Ding, Yu
    Zhang, Changkun
    Zhang, Leyuan
    Zhou, Yangen
    Yu, Guihua
    [J]. CHEMICAL SOCIETY REVIEWS, 2018, 47 (01) : 69 - 103
  • [7] Electrical Energy Storage for the Grid: A Battery of Choices
    Dunn, Bruce
    Kamath, Haresh
    Tarascon, Jean-Marie
    [J]. SCIENCE, 2011, 334 (6058) : 928 - 935
  • [8] A metal-free organic-inorganic aqueous flow battery
    Huskinson, Brian
    Marshak, Michael P.
    Suh, Changwon
    Er, Sueleyman
    Gerhardt, Michael R.
    Galvin, Cooper J.
    Chen, Xudong
    Aspuru-Guzik, Alan
    Gordon, Roy G.
    Aziz, Michael J.
    [J]. NATURE, 2014, 505 (7482) : 195 - +
  • [9] Dual function of quaternary ammonium in Zn/Br redox flow battery: Capturing the bromine and lowering the charge transfer resistance
    Jeon, Jae-Deok
    Yang, Hyeon Sun
    Shim, Joonmok
    Kim, Hyun Sik
    Yang, Jung Hoon
    [J]. ELECTROCHIMICA ACTA, 2014, 127 : 397 - 402
  • [10] A novel single flow zinc-bromine battery with improved energy density
    Lai, Qinzhi
    Zhang, Huamin
    Li, Xianfeng
    Zhang, Liqun
    Cheng, Yuanhui
    [J]. JOURNAL OF POWER SOURCES, 2013, 235 : 1 - 4