A quantum-mechanical study of the dynamics of the O(1D)+H2→OH+H insertion reaction

被引：101
|
作者：
Honvault, P [1 ]
Launay, JM [1 ]
机构：
[1] Univ Rennes 1, PALMS, CNRS, UMR 6627, Campus Beaulieu, F-35042 Rennes, France
来源：
JOURNAL OF CHEMICAL PHYSICS | 2001年 / 114卷 / 03期
关键词：
D O I：
10.1063/1.1338973
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
We have studied the quantum dynamics of the O(D-1)+H-2(X (1)Sigma (+)(g))--> OH(X (2)Pi)+H(S-2) reaction at low collision energies. The hyperspherical method has been used in a time-independent formalism. We present rotational and vibrational distributions. OH vibrational distributions are found to be noninverted. Differential cross sections are almost symmetric in the forward and backward directions, with a slight preference for forward scattering. These features are consistent with the formation of an intermediate complex. (C) 2001 American Institute of Physics.
引用
收藏
页码：1057 / 1059
页数：3
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