Performance of a proton exchange membrane fuel cell stack using conductive amorphous carbon-coated 304 stainless steel bipolar plates

被引:107
作者
Yi, Peiyun [1 ]
Peng, Linfa [1 ]
Feng, Lizhong [2 ]
Gan, Pin [2 ]
Lai, Xinmin [1 ]
机构
[1] Shanghai Jiao Tong Univ, State Key Lab Mech Syst & Vibrat, Shanghai 200240, Peoples R China
[2] SAIC Motor Corp Ltd, Shanghai 200041, Peoples R China
基金
中国国家自然科学基金;
关键词
Proton exchange membrane fuel cells; Bipolar plates; Amorphous carbon film; Stainless steel; Performance; GAS-DIFFUSION LAYER; STAINLESS-STEEL; CONTAMINATION; DEGRADATION; DURABILITY; MITIGATION; MECHANISMS; PEFC;
D O I
10.1016/j.jpowsour.2010.05.019
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this study, 304 stainless steel (SS) bipolar plates are fabricated by flexible forming process and an amorphous carbon (a-C) film is coated by closed field unbalanced magnetron sputter ion plating (CFUBMSIP). The interfacial contact resistance (ICR), in-plane conductivity and surface energy of the a-C coated 304SS samples are investigated. The initial performance of the single cell with a-C coated bipolar plates is 923.9 mW cm(-2) at a cell voltage of 0.6 V, and the peak power density is 1150.6 mW cm(-2) at a current density of 2573.2 mA cm(-2). Performance comparison experiments between a-C coated and bare 304SS bipolar plates show that the single cell performance is greatly improved by the a-Ccoating. Lifetime test of the single cell over 200 h and contamination analysis of the tested membrane electrode assemble (M EA) indicate that the a-C coating has excellent chemical stability. A 100 W-class proton exchange membrane fuel cell (PEMFC) short stack with a-C coated bipolar plates is assembled and shows exciting initial performance. The stack also exhibits uniform voltage distribution, good short-term lifetime performance, and high volumetric power density and specific power. Therefore, a-C coated 304SS bipolar plates may be practically applied for commercialization of PEMFC technology. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码:7061 / 7066
页数:6
相关论文
共 26 条
[1]   A review of PEM hydrogen fuel cell contamination: Impacts, mechanisms, and mitigation [J].
Cheng, Xuan ;
Shi, Zheng ;
Glass, Nancy ;
Zhang, Lu ;
Zhang, Jiujun ;
Song, Datong ;
Liu, Zhong-Sheng ;
Wang, Haijiang ;
Shen, Jun .
JOURNAL OF POWER SOURCES, 2007, 165 (02) :739-756
[2]   Characteristics of composite bipolar plates for polymer electrolyte membrane fuel cells [J].
Cho, EA ;
Jeon, US ;
Ha, HY ;
Hong, SA ;
Oh, IH .
JOURNAL OF POWER SOURCES, 2004, 125 (02) :178-182
[3]   Performance of a 1 kW-class PEMFC stack using TiN-coated 316 stainless steel bipolar plates [J].
Cho, EA ;
Jeon, US ;
Hong, SA ;
Oh, IH ;
Kang, SG .
JOURNAL OF POWER SOURCES, 2005, 142 (1-2) :177-183
[4]   Carbon film-coated 304 stainless steel as PEMFC bipolar plate [J].
Chung, Chih-Yeh ;
Chen, Shi-Kun ;
Chiu, Po-Jen ;
Chang, Ming-Hsin ;
Hung, Tien-Tsai ;
Ko, Tse-Hao .
JOURNAL OF POWER SOURCES, 2008, 176 (01) :276-281
[5]   Gas diffusion layer for proton exchange membrane fuel cells-A review [J].
Cindrella, L. ;
Kannan, A. M. ;
Lin, J. F. ;
Saminathan, K. ;
Ho, Y. ;
Lin, C. W. ;
Wertz, J. .
JOURNAL OF POWER SOURCES, 2009, 194 (01) :146-160
[6]   Stainless steel as a bipolar plate material for solid polymer fuel cells [J].
Davies, DP ;
Adcock, PL ;
Turpin, M ;
Rowen, SJ .
JOURNAL OF POWER SOURCES, 2000, 86 (1-2) :237-242
[7]   Bipolar plate materials for solid polymer fuel cells [J].
Davies, DP ;
Adcock, PL ;
Turpin, M ;
Rowen, SJ .
JOURNAL OF APPLIED ELECTROCHEMISTRY, 2000, 30 (01) :101-105
[8]   Preparation and properties of thin epoxy/compressed expanded graphite composite bipolar plates for proton exchange membrane fuel cells [J].
Du, Chao ;
Ming, Pingwen ;
Hou, Ming ;
Fu, Jie ;
Shen, Qiang ;
Liang, Dong ;
Fu, Yunfeng ;
Luo, Xiaokuan ;
Shao, Zhigang ;
Yi, Baolian .
JOURNAL OF POWER SOURCES, 2010, 195 (03) :794-800
[9]   Conductive amorphous carbon-coated 316L stainless steel as bipolar plates in polymer electrolyte membrane fuel cells [J].
Feng, Kai ;
Shen, Yao ;
Sun, Hailin ;
Liu, Donglan ;
An, Quanzhang ;
Cai, Xun ;
Chu, Paul K. .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2009, 34 (16) :6771-6777
[10]   Carbon-based films coated 316L stainless steel as bipolar plate for proton exchange membrane fuel cells [J].
Fu, Yu ;
Lin, Guoqiang ;
Hou, Ming ;
Wu, Bo ;
Shao, Zhigang ;
Yi, Baolian .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2009, 34 (01) :405-409