Mono- and dinuclear zinc complexes derived from unsymmetric binucleating ligands: Synthesis, characterization, and formation of tetranuclear arrays

被引:87
作者
Erxleben, A [1 ]
机构
[1] Univ Dortmund, Fachbereich Chem, D-44221 Dortmund, Germany
关键词
D O I
10.1021/ic000600z
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
An iron(III) complex of a novel tripodal tris-hydroxamate, tris[2-{(N-acetyl-N-hydroxy)glycylamino}ethyl]amine (TAGE), was synthesized as a siderophore model. Its X-ray structure revealed that intra- and interstrand hydrogen bonding networks cause an increase in the iron redox potential.
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页码:208 / 213
页数:6
相关论文
共 31 条
[1]   SYNTHESIS, STRUCTURE, AND SPECTROSCOPIC PROPERTIES OF COPPER(II) COMPOUNDS CONTAINING NITROGEN SULFUR DONOR LIGANDS - THE CRYSTAL AND MOLECULAR-STRUCTURE OF AQUA[1,7-BIS(N-METHYLBENZIMIDAZOL-2'-YL)-2,6-DITHIAHEPTANE]COPPER(II) PERCHLORATE [J].
ADDISON, AW ;
RAO, TN ;
REEDIJK, J ;
VANRIJN, J ;
VERSCHOOR, GC .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1984, (07) :1349-1356
[2]  
[Anonymous], 1990, IUPAC CHEM DATA SERI
[3]   SYNTHESIS AND X-RAY CRYSTAL-STRUCTURES OF NI-4 AND ZN-4 COMPLEXES OF A MACROCYCLIC TETRANUCLEATING LIGAND [J].
BELL, M ;
EDWARDS, AJ ;
HOSKINS, BF ;
KACHAB, EH ;
ROBSON, R .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (10) :3603-3610
[4]   SIMULATION STRATEGIES FOR UNUSUAL EPR-SPECTRA OF BINUCLEAR MIXED-VALENCE MANGANESE COMPLEXES - SYNTHESIS, PROPERTIES, AND X-RAY STRUCTURES OF THE MNIIMNIII COMPLEXES [MN2(BPMP)(MU-OAC)2](CLO4)2.H2O AND [MN2(BCMP)(MU-OAC)2](CLO4)2.CH2CL2 [J].
DIRIL, H ;
CHANG, HR ;
NILGES, MJ ;
ZHANG, XH ;
POTENZA, JA ;
SCHUGAR, HJ ;
ISIED, SS ;
HENDRICKSON, DN .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (14) :5102-5114
[5]   Reactions between hexamethylenetetramine and phenolic compounds Part I A new method for the preparation of 3-and 5-aldehydosalicylic acids [J].
Duff, JC ;
Bills, EJ .
JOURNAL OF THE CHEMICAL SOCIETY, 1932, :1987-1987
[6]   Unsymmetric dinucleating ligands for metallobiosite modelling [J].
Fenton, DE ;
Okawa, H .
CHEMISCHE BERICHTE-RECUEIL, 1997, 130 (04) :433-442
[7]   Dinuclear iron(III)-metal(II) complexes as structural core models for purple acid phosphatases [J].
Ghiladi, M ;
McKenzie, CJ ;
Meier, A ;
Powell, AK ;
Ulstrup, J ;
Wocadlo, S .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1997, (21) :4011-4018
[8]   Synthesis, crystal structure and solution behavior of a novel tetranuclear Zn(II) Schiff base complex [J].
Hermann, J ;
Erxleben, A .
INORGANICA CHIMICA ACTA, 2000, 304 (01) :125-129
[9]   MODELS FOR IRON OXO PROTEINS - MOSSBAUER AND EPR STUDY OF AN ANTIFERROMAGNETICALLY COUPLED FE-III NI-II COMPLEX [J].
HOLMAN, TR ;
JUAREZGARCIA, C ;
HENDRICH, MP ;
QUE, L ;
MUNCK, E .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (21) :7611-7618
[10]   Dinuclear nickel(II) complexes of phenol-based "end-off" compartmental ligands and their urea adducts relevant to the urease active site [J].
Koga, T ;
Furutachi, H ;
Nakamura, T ;
Fukita, N ;
Ohba, M ;
Takahashi, K ;
Okawa, H .
INORGANIC CHEMISTRY, 1998, 37 (05) :989-996