Expanding the Pillararene Chemistry: Synthesis and Application of a 10+1 Functionalized Pillar[5]arene

被引：36

作者：

Bojtar, Marton ^{[1
]}

Simon, Andras ^{[2
]}

Bombicz, Petra ^{[3
]}

Bitter, Istvan ^{[1
]}

机构：

[1] Budapest Univ Technol & Econ, Dept Organ Chem & Technol, H-1521 Budapest, Hungary

[2] Budapest Univ Technol & Econ, Dept Inorgan & Analyt Chem, H-1521 Budapest, Hungary

[3] Hungarian Acad Sci, Res Ctr Nat Sci, H-1519 Budapest, Hungary

来源：

ORGANIC LETTERS | 2017年 / 19卷 / 17期

基金：

匈牙利科学研究基金会;

关键词：

HOST-GUEST COMPLEXATION; SELF-INCLUSION BEHAVIOR; RAY CRYSTAL-STRUCTURE; MOLECULAR RECOGNITION; WATER; CALIXARENES; OXIDATION; ATP;

D O I：

10.1021/acs.orglett.7b02092

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A novel functionality was introduced in the pillararene family by the Claisen rearrangement of monoallyl pillar[S]arene. This new key derivative can lead to the formation of a 10 + 1 functionalized derivative, a useful scaffold for further derivatization. Except for the previously known monodeprotection reaction, all steps proceed efficiently with high yields and easy separation. In addition, a solvent responsive pseudo[1]rotaxane was synthesized based on this novel functionality.

引用

页码：4528 / 4531

页数：4

共 43 条

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