Excess molar enthalpies of ethyl acetoacetate plus (methanol, +ethanol, +1-propanol, and +2-propanol) at T = (298.15, 313.15 and 328.15) K and p = (0.1 and 10.0) MPa

被引：8

作者：

Gao, Hui ^{[1
]}

Li, Shengying ^{[1
]}

Yan, Weidong ^{[1
]}

机构：

[1] Zhejiang Univ, Dept Chem, Hangzhou 310027, Zhejiang, Peoples R China

来源：

FLUID PHASE EQUILIBRIA | 2008年 / 268卷 / 1-2期

关键词：

excess molar enthalpy; density; ethyl acetoacetate; alcohols; NRTL; UNIQUAC;

D O I：

10.1016/j.fluid.2008.03.012

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The excess molar enthalpies of four binary systems for ethyl acetoacetate +(methanol, +ethanol, +1-propanol, and +2-propanol) at T= (298.15,313.15, and 328.15) K and p = (0.1 and 10.0) MPa were determined by a high pressure flow-mixing isothermal microcalorimeter. The densities of ethyl acetoacetate at T=(278.15, 288.15, 298.15, 313.15, 328.15, 338.15, and 348.15)K were determined by pycnometer. The excess molar enthalpies increase with an increase in the temperature and the molecular size of alcohols and decrease with an increase in pressure. The experimental data were correlated by the Redlich-Kister equation and two local composition models (NRTL and UNIQUAC). (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：34 / 38

页数：5

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