Metal-Organic Frameworks Incorporating Copper-Complexed Rotaxanes

被引：95

作者：

Coskun, Ali ^{[1
,3
,4
]}

Hmadeh, Mohamad ^{[2
]}

Barin, Gokhan ^{[1
]}

Gandara, Felipe ^{[2
]}

Li, Qiaowei ^{[2
]}

Choi, Eunwoo ^{[2
]}

Strutt, Nathan L. ^{[1
]}

Cordes, David B. ^{[6
,7
]}

Slawin, Alexandra M. Z. ^{[6
,7
]}

Stoddart, J. Fraser ^{[1
,3
,4
]}

Sauvage, Jean-Pierre ^{[1
,5
]}

Yaghi, Omar M. ^{[2
,3
,4
]}

机构：

[1] Northwestern Univ, Dept Chem, Evanston, IL 60208 USA

[2] Univ Calif Los Angeles, Dept Chem & Biochem, Los Angeles, CA 90095 USA

[3] Korea Adv Inst Sci & Technol, NanoCentury KAIST Inst, Taejon 305701, South Korea

[4] Korea Adv Inst Sci & Technol, Grad Sch EEWS WCU, Taejon 305701, South Korea

[5] Univ Strasbourg, Inst Sci & Ingn Supramol, F-67000 Strasbourg, France

[6] Univ St Andrews, Sch Chem, St Andrews KY16 9ST, Fife, Scotland

[7] Univ St Andrews, Ctr Bimol Sci, St Andrews KY16 9ST, Fife, Scotland

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 09期

基金：

美国国家科学基金会; 美国国家卫生研究院; 英国工程与自然科学研究理事会;

关键词：

interpenetrated networks; mechanostereochemistry; metal-organic frameworks; reticular chemistry; rotaxanes; CROWN-ETHER WHEELS; 2-DIMENSIONAL POLYROTAXANE; RETICULAR CHEMISTRY; TEMPLATED SYNTHESIS; MOLECULES; LIGANDS; CATENANDS; CHANNELS; CAVITIES; MOTIONS;

D O I：

10.1002/anie.201107873

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

MOFs on the move: A copper-coordinated [2]pseudorotaxanate which reacts with zinc nitrate to form threefold interpenetrated networks retains most of its solution-state chemistry, including its ability to undergo electronic switching of some of the copper(I) ions under redox control. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：2160 / 2163

页数：4

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