N, S doped carbon dots-Plasmonic Au nanocomposites for visible-light photocatalytic reduction of nitroaromatics

Herein, we report N, S co-doped carbon dots (NS CDs) as stabilizing and reducing agents for the synthesis of N, S doped carbon dots-Au nanocomposites (NS CDs-Au NCs) through the solution method and explore the catalytic property of the synthesized nanocomposites in the reduction of nitro aromatic compounds (NACs) such as 4-nitrophenol (4-NP), 4-nitroaniline (4-NA), and nitrobenzene (NB). The appraisal of the catalytic efficacy of the NS CDs-Au NCs was premised on real time monitoring of the reduction of NACs using UV-Visible absorption spectroscopy. The apparent rate constants (k(app)) of reduction were found to follow the pseudo-first-order kinetics having values of 1.37 x 10(-1), 8.9 x 10(-2), and 5.35 x 10(-2) s(-1) for 4-NP, 4-NA, and NB, respectively. The apparent rate constant (1.37 x 10(-1) s(-1)) observed for the reduction of 4-NP by NaBH4 using NS CDs-Au NCs has been found to be one of the highest values reported in the literature so far thereby validating their excellent efficacy as a catalyst.