Generation and intermolecular reactions of 2-indolylacyl radicals

被引：32

作者：

Bennasar, ML ^{[1
]}

Roca, T ^{[1
]}

Griera, R ^{[1
]}

Bosch, J ^{[1
]}

机构：

[1] Univ Barcelona, Fac Pharm, Organ Chem Lab, E-08028 Barcelona, Spain

来源：

ORGANIC LETTERS | 2001年 / 3卷 / 11期

关键词：

D O I：

10.1021/ol0100576

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The generation of 2-indolylacyl radicals from the corresponding phenyl selenoesters, aldehydes, and cr keto carboxylic acids and the scope of their participation in intermolecular addition reactions to carbon-carbon double bonds have been studied. Whereas the phenyl selenoester method has provided easy access to a variety of 1,4-dicarbonyl compounds bearing the 2-acylindole moiety, the glyoxylic acid route has been employed for the preparation of 2-indolyl pyridyl ketones.

引用

页码：1697 / 1700

页数：4

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