Solvothermally reduced graphene oxide/polyimide composites: Structures and thermal and mechanical properties

被引:7
作者
Zhang, Xin [1 ]
Ma, Yahui [2 ]
Pei, Yingjin [2 ]
Zheng, Shuojin [2 ]
Fang, Qinghong [2 ]
Li, Yao [3 ]
Niu, Yongan [2 ,3 ]
机构
[1] Shenyang Univ Chem Technol, Sch Chem Engn, Shenyang 150040, Liaoning, Peoples R China
[2] Shenyang Univ Chem Technol, Sch Mat Sci & Engn, Shenyang 150040, Liaoning, Peoples R China
[3] Harbin Inst Technol, Ctr Composite Mat, Harbin 150001, Heilongjiang, Peoples R China
基金
中国国家自然科学基金;
关键词
composites; nanotubes; graphene; and fullerenes; nonpolymeric materials and composites; IN-SITU POLYMERIZATION; ELECTRICAL-PROPERTIES; OXIDE SHEETS; REDUCTION; NANOCOMPOSITES; EVOLUTION;
D O I
10.1002/app.47164
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Solvothermally reduced graphene oxide (SRGO)/polyimide (PI) composites were prepared by in situ polymerization. The structures and components were carefully investigated by X-ray diffraction. Thermal properties were measured by thermogravimetry and dynamic thermomechanical analysis. Mechanical properties were carefully evaluated by tensile testing and scanning electron microscopy. The SRGO/PI composites exhibit extremely high tensile strength and elastic modulus, which is 30% higher than that of pure PI film. Meanwhile, the thermal stability of SRGO/PI composites also displays an obvious enhancement. (c) 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019, 136, 47164.
引用
收藏
页数:6
相关论文
共 29 条
[1]   Preparation of graphene by pressurized oxidation and multiplex reduction and its polymer nanocomposites by masterbatch-based melt blending [J].
Bao, Chenlu ;
Song, Lei ;
Xing, Weiyi ;
Yuan, Bihe ;
Wilkie, Charles A. ;
Huang, Jianliu ;
Guo, Yuqiang ;
Hu, Yuan .
JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (13) :6088-6096
[2]   Enhanced stress transfer and thermal properties of polyimide composites with covalent functionalized reduced graphene oxide [J].
Cao, Li ;
Sun, Qingqing ;
Wang, Haixia ;
Zhang, Xingxiang ;
Shi, Haifeng .
COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING, 2015, 68 :140-148
[3]   Highly selective adsorption of Hg2+ by a polypyrrole-reduced graphene oxide composite [J].
Chandra, Vimlesh ;
Kim, Kwang S. .
CHEMICAL COMMUNICATIONS, 2011, 47 (13) :3942-3944
[4]   In Situ Thermal Preparation of Polyimide Nanocomposite Films Containing Functionalized Graphene Sheets [J].
Chen, Dan ;
Zhu, Hong ;
Liu, Tianxi .
ACS APPLIED MATERIALS & INTERFACES, 2010, 2 (12) :3702-3708
[5]   In situ random co-polycondensation for preparation of reduced graphene oxide/polyimide nanocomposites with amino-modified and chemically reduced graphene oxide [J].
Chen, Wen-Qiu ;
Li, Quan-Tao ;
Li, Peng-Hui ;
Zhang, Quan-Yuan ;
Xu, Zu-Shun ;
Chu, Paul K. ;
Wang, Xian-Bao ;
Yi, Chang-Feng .
JOURNAL OF MATERIALS SCIENCE, 2015, 50 (11) :3860-3874
[6]   Graphene Oxide, Highly Reduced Graphene Oxide, and Graphene: Versatile Building Blocks for Carbon-Based Materials [J].
Compton, Owen C. ;
Nguyen, SonBinh T. .
SMALL, 2010, 6 (06) :711-723
[7]   Relationship between microstructure of lamellar graphene sheets and properties of polyimide/graphene nanocomposites film under different imidization stages [J].
Ding, Xin ;
Zhang, Xian ;
Bao, Chao ;
Tan, Su ;
Zheng, Kang ;
Chen, Lin ;
Zhang, Hui ;
Tian, Xingyou .
JOURNAL OF APPLIED POLYMER SCIENCE, 2016, 133 (25)
[8]   The chemistry of graphene oxide [J].
Dreyer, Daniel R. ;
Park, Sungjin ;
Bielawski, Christopher W. ;
Ruoff, Rodney S. .
CHEMICAL SOCIETY REVIEWS, 2010, 39 (01) :228-240
[9]   The rise of graphene [J].
Geim, A. K. ;
Novoselov, K. S. .
NATURE MATERIALS, 2007, 6 (03) :183-191
[10]   Synthesis and electrochromic properties of aromatic polyimides bearing pendent triphenylamine units [J].
Hsiao, Sheng-Huei ;
Chou, Yu-Tan .
POLYMER, 2014, 55 (10) :2411-2421