Synthesis and Crystal Structure of a New Mn8 Compound with Tripodal Ligand

被引：0

作者：

Li Na ^{[1
,2
]}

Ma Cheng-Bing ^{[1
]}

Wang Mei ^{[1
]}

Zhou Rong-Wei ^{[1
,2
]}

Hu Ming-Qiang ^{[1
]}

Chen Chang-Neng ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China

[2] Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China

来源：

CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2010年 / 29卷 / 11期

基金：

中国国家自然科学基金;

关键词：

manganese compound; crystal structure; tripodal ligand; SINGLE-MOLECULE MAGNET; MANGANESE CARBOXYLATE CHEMISTRY; PHOTOSYSTEM-II; GROUND-STATE; CLUSTER; COMPLEXES; DECANUCLEAR; RELEVANCE; OXIDATION; POLYMER;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new manganese compound [Mn-8(tmp)(2)(Htmp)(4)((CH3)(3)CCO2)(4)(py)(2)Cl-2]center dot 2py (1.2py, H(3)tmp = 1,1,1-tri(hydroxymethyl)propane, py = pyramid) has been synthesized and its structure was characterized by IR, elemental analysis and X-ray diffraction. Compound 1 belongs to the triclinic system, space group P (1) over bar with a = 13.378(5), b = 14.334(5), c = 15.012(6) angstrom, alpha = 107.637(5) beta = 95.635(3), gamma = 92.825(4), V = 2720.7(17) angstrom(3), Z = 1, C(76)H(124)N(4)O(26)C1(2)Mn(8), M-r = 2022.23, D-c = 1.234 Mg/m(3), mu = 1.007 mm(-1), F(000) = 1052, T = 293(2) K, the final R = 0.0755 and wR = 0.2163 for all 6463 observed reflections (I > 2 sigma(I)). X-ray analysis shows that the core of 1 contains a [Mn-8] mixed-valence rod-like unit consisting of six edge-sharing triangles (Mn-3), each of which is bridged by a mu(3)-oxygen atom.

引用

页码：1731 / 1735

页数：5

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