Dynamic extension-contraction motion in supramolecular springs

被引:115
作者
Kim, Ho-Joong [1 ]
Lee, Eunji [1 ]
Park, Hye-Seo [1 ]
Lee, Myongsoo [1 ]
机构
[1] Yonsei Univ, Ctr Supramol Nano Assembly, Dept Chem, Seoul 120749, South Korea
关键词
D O I
10.1021/ja073554b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We have prepared coordination polymers with bent conformations that adopt a helical structure with reversible extension-contraction motions, triggered by temperature. Furthermore, this dynamic conformational change leads to a fluorescence switching between the fluorescent stretched and nonfluorescent compressed states of the supramolecular springs.
引用
收藏
页码:10994 / +
页数:3
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