A novel change of light transmission in supercooled liquid state of ethylbenzene

被引：15

作者：

Ishii, K ^{[1
]}

Okamura, T ^{[1
]}

Ishikawa, N ^{[1
]}

Nakayama, H ^{[1
]}

机构：

[1] Gakushuin Univ, Dept Chem, Toshima Ku, Tokyo 1718588, Japan

来源：

CHEMISTRY LETTERS | 2001年 / 01期

关键词：

D O I：

10.1246/cl.2001.52

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

By the continuous elevation of temperature, ethylbenzene in the supercooled liquid state first turns opaque and then becomes transparent again before it finally crystallizes. These observations are possibly related to the appearance of the second amorphous state with a correlated structure that has recently been reported for triphenyl phosphite.

引用

页码：52 / 53

页数：2

共 11 条

[1] STRUCTURAL INSTABILITY AND RELAXATION IN LIQUID AND GLASSY PHASES NEAR THE FRAGILE LIQUID LIMIT [J].

ANGELL, CA .

JOURNAL OF NON-CRYSTALLINE SOLIDS, 1988, 102 (1-3) :205-221

[2] FORMATION OF GLASSES FROM LIQUIDS AND BIOPOLYMERS [J].

ANGELL, CA .

SCIENCE, 1995, 267 (5206) :1924-1935

[3] A low-temperature amorphous phase in a fragile glass-forming substance [J].

Cohen, I ;

Ha, A ;

Zhao, XL ;

Lee, M ;

Fischer, T ;

Strouse, MJ ;

Kivelson, D .

JOURNAL OF PHYSICAL CHEMISTRY, 1996, 100 (20) :8518-8526

[4] Supercooled liquids and polyamorphism [J].

Ha, A ;

Cohen, I ;

Zhao, XL ;

Lee, M ;

Kivelson, D .

JOURNAL OF PHYSICAL CHEMISTRY, 1996, 100 (01) :1-4

[5] Raman signature of polyamorphism in triphenyl phosphite [J].

Hedoux, A ;

Guinet, Y ;

Descamps, M .

PHYSICAL REVIEW B, 1998, 58 (01) :31-34

[6] Amorphous state of vacuum-deposited benzene and its crystallization [J].

Ishii, K ;

Nakayama, H ;

Yoshida, T ;

Usui, H ;

Koyama, K .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1996, 69 (10) :2831-2838

[7]

ISHII K, IN PRESS

[8] Presence of two freezing-in processes concerning α-glass transition in the new liquid phase of triphenyl phosphite and its consistency with "cluster structure" and "intracluster rearrangement for α process" models [J].

Mizukami, M ;

Kobashi, K ;

Hanaya, M ;

Oguni, M .

JOURNAL OF PHYSICAL CHEMISTRY B, 1999, 103 (20) :4078-4088

[9]

Nakayama H, 1997, J RAMAN SPECTROSC, V28, P15, DOI 10.1002/(SICI)1097-4555(199701)28:1<15::AID-JRS56>3.0.CO

[10]

2-W

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