Green Baeyer-Villiger oxidation with hydrogen peroxide:: Sn[N(SO2C8F17)2]4 as a highly selective Lewis acid catalyst in a fluorous biphase system

被引：32

作者：

Hao, XH

Yamazaki, O

Yoshida, A

Nishikido, J ^{[1
]}

机构：

[1] Noguchi Inst, Itabashi Ku, Tokyo 1730003, Japan

[2] Japan Chem Innovat Inst, Itabashi Ku, Tokyo 1730003, Japan

来源：

GREEN CHEMISTRY | 2003年 / 5卷 / 05期

关键词：

D O I：

10.1039/b304439d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In a fluorous biphasic catalytic system for Baeyer-Villiger oxidation of cyclic ketones, it was shown that Sn[N(SO2C8F17)(2)](4) catalyst can give an excellent yield and selectivity with the green, safe and cheap 35% aqueous hydrogen peroxide as the oxidant. Furthermore, it was also found that the catalyst can be completely recovered and reused without loss of its activity in the fluorous immobilized phase.

引用

页码：524 / 528

页数：5

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