Experimental studies on polyethylene oxide-NaClO4 based composite polymer electrolytes dispersed with Na2SiO3

被引：62

作者：

Hashmi, SA ^{[1
]}

Thakur, AK ^{[1
]}

Upadhyaya, HM ^{[1
]}

机构：

[1] N Eastern Reg Inst Sci & Technol, Dept Phys, Itanagar 791109, Nirjuli, India

来源：

EUROPEAN POLYMER JOURNAL | 1998年 / 34卷 / 09期

关键词：

D O I：

10.1016/S0014-3057(97)00269-3

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Composite polymer electrolytes comprising of a poly ethylene oxide (PEO)-NaClO4 complex dispersed with Na2SiO3 are described. The results of the studies based on optical microscopy, X-ray diffraction, differential scanning calorimetry, a.c. impedance analysis and mechanical testing are presented and discussed. An electrical conductivity of 1.02 x 10(-3) S cm(-1) at 100 degrees C was achieved with a dispersion of 1 wt% of Na2SiO3. A substantial enhancement in the mechanical proper:ies of the composite films was observed at the cost of a slight decrease in the conductivity. The temperature dependence of conductivity follows an Arrhenius type thermally activated process below and above the melting temperature of PEO. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：1277 / 1282

页数：6

共 17 条

[1] COMPOSITE POLYMER ELECTROLYTES
CAPUANO, F
CROCE, F
SCROSATI, B
[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1991, 138 (07) : 1918 - 1922
[2] Effects of SiC fillers on the electrical and mechanical properties of (PEO)(16)LiClO4 electrolytes
Choi, BK
Shin, KH
[J]. SOLID STATE IONICS, 1996, 86-8 : 303 - 306
[3] PROPERTIES OF MIXED POLYMER AND CRYSTALLINE IONIC CONDUCTORS
CROCE, F
BONINO, F
PANERO, S
SCROSATI, B
[J]. PHILOSOPHICAL MAGAZINE B-PHYSICS OF CONDENSED MATTER STATISTICAL MECHANICS ELECTRONIC OPTICAL AND MAGNETIC PROPERTIES, 1989, 59 (01): : 161 - 168
[4] LITHIUM POLYMER ELECTROLYTE RECHARGEABLE BATTERY
FAUTEUX, D
MASSUCCO, A
MCLIN, M
VANBUREN, M
SHI, J
[J]. ELECTROCHIMICA ACTA, 1995, 40 (13-14) : 2185 - 2190
[5] Gray FM., 1991, POLYM ELECTROLYTES F
[6] Linford R.G., 1987, ELECTROCHEMICAL SCI, V1
[7] MacCallum J.R., 1989, POLYM ELECTROLYTE RE, V2
[8] MacCallum J. R., 1987, POLYM ELECTROLYTE RE, V1
[9] Polymer-ceramic ion-conducting composites
Nairn, K
Forsyth, M
Every, H
Greville, M
MacFarlane, DR
[J]. SOLID STATE IONICS, 1996, 86-8 : 589 - 593
[10] PEO based composite solid electrolyte containing NASICON
Plocharski, J.
Wieczorek, W.
[J]. Solid State Ionics, 1988, 28-30 : 979 - 982

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