Synthesis and crystal structure of the novel trimanganese tetrathiolate incomplete cubane:: [Mo(η5-C5H5)2(H)CO][Mn3(CO)9(μ-SC6H5)4]

被引：4
作者：
Dias, AR
Galvao, A
Garcia, MH
de Brito, MJV
机构：
[1] Inst Super Tecn, Ctr Quim Estrutural, P-1049001 Lisbon, Portugal
[2] Univ Lisbon, Fac Ciencias, DQB, P-1749016 Lisbon, Portugal
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2001年 / 620卷 / 1-2期
关键词：
trinuclear; manganese incomplete cubane; thiolate-bridged; molybdenum biscyclopentadienyl; carbonyl; hydride;
D O I：
10.1016/S0022-328X(00)00798-1
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
An unexpected trimanganese(I) tetrathiolate-bridged complex, [Mn-3(CO)(9)(mu -SC6H5)(4)](-), with an incomplete cubane structure, was obtained by thermal reaction of [Mn-2(CO)(10)] with [Mo(eta (5)-C5H5)(2)(SC6H5)(2)]. The structure, established by single-crystal X-ray diffraction studies, shows the cation, [Mo(eta (5)-C(5)H5)(2)(H)CO](+), directed towards the vacant site of the cubane structure. Possible routes by which the anion and the cation could be formed are discussed. (C) 2001 Elsevier Science B.V. All rights reserved.
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页码：276 / 281
页数：6
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